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RETRACTED ARTICLE: Bifunctional (3,6)-Connected Gd(III) Metal–Organic Framework Material with Catalytic Properties for the Cyanosilylation Reaction and Anti-gastric Cancer Activity

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This article was retracted on 29 January 2024

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Abstract

A new Gd(III) coordination polymer, namely [Gd(bpt)(H2O)(DMF)]n·3n(H2O) (1, H3bpt = biphenyl-3,4′,5-tricarboxylic acid, DMF = N,N-dimethylformamide), has been successfully synthesized under solvothermal conditions. In the structure of 1, the dinuclear [Gd2(COO)4] building subunits are connected by the bpt3− ligands into a 3D framework with (3,6)-connected flu-3,6-C2/c topology. Moreover, the catalytic performances of 1 and 1′ (desolvated sample) towards the cyanosilylation of benzaldehyde and its derivatives have been tested under mild conditions. The catalytic activity of 1′ is higher than that of compound 1, indicating that more open metal sites in coordination polymer is beneficial to the cyanosilylation reaction. In addition, in vitro anticancer activities of compounds 1 and 1′ (desolvated sample) on four human gastric cancer cells (MGC-803, SGC-790, MKN45 and AGS) were further determined.

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Authors and Affiliations

  1. Department of Gastrology, The First Affiliated Hospital of Wenzhou Medical University, Wenzhou, Zhejiang, China

    Zhou-Feng Chen, Hai-Bo Xue, Lei-Ruo Wu & Rui-Fang Jin

Authors
  1. Zhou-Feng Chen
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  2. Hai-Bo Xue
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  3. Lei-Ruo Wu
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  4. Rui-Fang Jin
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Correspondence to Rui-Fang Jin.

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Chen, ZF., Xue, HB., Wu, LR. et al. RETRACTED ARTICLE: Bifunctional (3,6)-Connected Gd(III) Metal–Organic Framework Material with Catalytic Properties for the Cyanosilylation Reaction and Anti-gastric Cancer Activity. J Clust Sci 29, 1269–1274 (2018). https://doi.org/10.1007/s10876-018-1445-8

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  • DOI: https://doi.org/10.1007/s10876-018-1445-8

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