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The New Arsenomolybdate Based on Monocapped Trivacant Keggin {H4AsIIIAsVMo9O34} Cluster and Cu–abi Complex: Synthesis, Structure, Photoluminescence and Catalysis Properties

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Abstract

A new organic–inorganic hybrid arsenomolybdate, formulated as, [{Cu(abi){H4AsIIIAsVMo9O34}](abi)4[Cu(abi)2]·H2O (1) (abi = 2-aminobenzimidazole) has been hydrothermally synthesized and structurally characterized by the elemental analysis, TG, IR, XRD, UV and single-crystal X-ray diffraction. Compound 1 represents the first example of monocapped trivacant Keggin {H4AsIIIAsVMo9O34}2− cluster as polydentate ligand linked to Cu–abi complexes and abi ligands through one covalent bond and fourteen hydrogen bonds. Compound 1 possesses two different four rings, which forms a 3D topology framework with schläfli symbol of {46·6·8·1820}{4}2{6}2{8}3. The photoluminescence and photocatalysis properties of 1 have been investigated. Moreover, we performed evaluation on its catalytic activity towards the hydrolysis of ethylene carbonate to produce ethylene glycol.

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Acknowledgements

This work was supported by the Natural Science Foundation of Heilongjiang Province (No. QC2015011).

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Authors and Affiliations

  1. College of Material Science and Engineering, Heilongjiang University of Science and Technology, Harbin, 150022, China

    Zhifeng Zhao & Wei Gao

  2. Key Laboratory of Photochemical Biomaterials and Energy Storage Materials, Heilongjiang Province, College of Chemistry and Chemical Engineering, Harbin Normal University, Harbin, 150025, China

    Zhanhua Su, Bowen Cong & Xiujuan Ma

Authors
  1. Zhifeng Zhao
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  2. Zhanhua Su
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  3. Bowen Cong
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  4. Wei Gao
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  5. Xiujuan Ma
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Correspondence to Zhifeng Zhao or Zhanhua Su.

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Zhao, Z., Su, Z., Cong, B. et al. The New Arsenomolybdate Based on Monocapped Trivacant Keggin {H4AsIIIAsVMo9O34} Cluster and Cu–abi Complex: Synthesis, Structure, Photoluminescence and Catalysis Properties. J Clust Sci 29, 943–949 (2018). https://doi.org/10.1007/s10876-018-1390-6

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  • DOI: https://doi.org/10.1007/s10876-018-1390-6

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