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Triangular Clusters of Molybdenum Coordinated with Diethylthiocarbamate: Synthesis, Structure and Solution Behavior

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Abstract

Two novel clusters [Mo3S4(dtc)3(μ-dtc)(L)] (where L = (CD3)2SO and tetrahydrothiophene, tht) were prepared and structurally characterized. The tht complex and its previously reported congener with L = py were studied by means of temperature-dependent 1H NMR spectroscopy, indicating order of lability tht ≫ py.

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Scheme 1
Scheme 2
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Fig. 2

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Notes

  1. The sample was dried in vacuum prior to analysis.

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Acknowledgements

This work was supported by the Russian Foundation for Basic Research (project 17-03-00663).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry SB RAS, Lavrentieva Av. 3, Novosibirsk, Russian Federation, 630090

    Pavel A. Petrov, Marsel R. Gallyamov, Aleksandra Yu. Andreeva, Taisiya S. Sukhikh & Maxim N. Sokolov

  2. Novosibirsk State University, Pirogova St. 2, Novosibirsk, Russian Federation, 630090

    Pavel A. Petrov, Elena A. Golubitskaya, Taisiya S. Sukhikh & Maxim N. Sokolov

  3. Kazan Federal University, Kremlyovskaya St. 18, Kazan, Russian Federation, 420008

    Maxim N. Sokolov

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  1. Pavel A. Petrov
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  2. Elena A. Golubitskaya
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  3. Marsel R. Gallyamov
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  4. Aleksandra Yu. Andreeva
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Correspondence to Pavel A. Petrov.

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Petrov, P.A., Golubitskaya, E.A., Gallyamov, M.R. et al. Triangular Clusters of Molybdenum Coordinated with Diethylthiocarbamate: Synthesis, Structure and Solution Behavior. J Clust Sci 29, 451–457 (2018). https://doi.org/10.1007/s10876-018-1350-1

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  • DOI: https://doi.org/10.1007/s10876-018-1350-1

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