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A Rare Heterobimetallic Ca–Ag Coordination Polymer as Sensitive Luminescence Sensor for TNP

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Abstract

The present work reports the synthesis, characterization, and crystal structure of a rare 2-D heterobimetallic Ca–Ag coordination polymer (CP) [Ca(DMF)4Ag2(SCN)4]n (1) (DMF = N,N-dimethylformamide). 1 is constructed by Ca metallic atoms, Ag2 dinuclear cluster, and SCN− bridges. This Ca–Ag CP exhibits strong luminescence property in its DMF suspension, and has been exploited as a highly sensitive sensor for the detection of TNP. Moreover, the energy-transfer mechanism of 1 for sensing TNP had been preliminarily elucidated.

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Acknowledgements

The authors gratefully acknowledged the National Natural Science Foundation (21607063, 21676129), China Postdoctoral Science Foundation (No. 2016M590421) and the Science and Technology Support Project of Zhenjiang (GY2017001, YE201709, and GY2016021).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, 212013, People’s Republic of China

    Xiulian Yin, Suci Meng & Jimin Xie

  2. School of Energy & Power Engineering, Jiangsu University, Zhenjiang, 212013, People’s Republic of China

    Xiulian Yin

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  1. Xiulian Yin
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  2. Suci Meng
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  3. Jimin Xie
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Correspondence to Jimin Xie.

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Yin, X., Meng, S. & Xie, J. A Rare Heterobimetallic Ca–Ag Coordination Polymer as Sensitive Luminescence Sensor for TNP. J Clust Sci 29, 411–416 (2018). https://doi.org/10.1007/s10876-018-1344-z

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  • DOI: https://doi.org/10.1007/s10876-018-1344-z

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