Skip to main content
SpringerLink
Log in

A Cuboidal Tetranuclear Nickel Cluster Based on O,O,N-Tridentate Schiff Base: Synthesis, Structure and Magnetic Properties

  • Original Paper
  • Published:
Journal of Cluster Science Aims and scope Submit manuscript

Abstract

One tetranuclear nickel cluster [Ni4L4(CH3CH2OH)4] (1, H2L = N-(2-hydroxyphenyl)salicylaldimino) was synthesized by solvothermally reaction and characterized by elemental analysis, IR, TGA and X-ray single-crystal diffraction. It exhibits a cubane-type [Ni4O4] structure with four Schiff base ligands and four alcohol molecules in the unit. Magnetic susceptibility studies indicate that there are ferromagnetic interactions within the tetranuclear nickel(II) cluster. Furthermore, Thermogravimetric analyses display the stability of complex 1.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Scheme 1
Fig. 1
Fig. 2
Scheme 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. P. Buchwalter, J. Rosé, and P. Braunstein (2015). Chem. Rev. 115, 28.

    Article  CAS  Google Scholar 

  2. S. C. Lee, W. Lo, and R. H. Holm (2014). Chem. Rev. 114, 3579.

    Article  CAS  Google Scholar 

  3. Y. H. Liu, L. P. Lu, M. L. Zhu, S. S. Feng, and F. Su (2016). Dalton Trans. 45, 9267.

    Article  CAS  Google Scholar 

  4. X. L. Wang, C. Qin, E. B. Wang, Z. M. Su, Y. G. Li, and L. Xu (2006). Angew. Chem. Int. Ed. 45, 7411.

    Article  CAS  Google Scholar 

  5. Y. L. Zhou, M. H. Zeng, L. Q. Wei, B. W. Li, and M. Kurmoo (2010). Chem. Mater. 22, 4295.

    Article  CAS  Google Scholar 

  6. Y. Z. Zhang, W. Wernsdorfer, F. Pan, Z. M. Wang, and S. Gao (2006). Chem. Commun. 31, 3302.

    Article  Google Scholar 

  7. L. L. Liang, L. Xu, Y. C. Xue, F. J. Chen, and H. B. Du (2015). Inorg. Chem. Commun. 62, 98.

    Article  CAS  Google Scholar 

  8. K. Singh, M. S. Barwa, and P. Tyagi (2007). Eur. J. Med. Chem. 42, 394.

    Article  CAS  Google Scholar 

  9. Z. L. You and H. L. Zhu (2004). Z. Anorg. Allg. Chem. 630, 2754.

    Article  CAS  Google Scholar 

  10. L. Shi, H. M. Ge, S. H. Tan, H. Q. Li, Y. C. Song, H. L. Zhu, and R. X. Tan (2007). Eur. J. Med. Chem. 42, 558.

    Article  CAS  Google Scholar 

  11. P. G. Cozzi (2004). Chem. Soc. Rev. 33, 410.

    Article  CAS  Google Scholar 

  12. F. S. Han (2013). Chem. Soc. Rev. 42, 5270.

    Article  CAS  Google Scholar 

  13. Y. Xiao, Y. Qin, M. Yi, and Y. Zhu (2016). J. Clust. Sci. 27, 2013.

    Article  CAS  Google Scholar 

  14. A. Majumder, G. M. Rosair, A. Mallick, N. Chattopadhyay, and S. Mitra (2006). Polyhedron 25, 1753.

    Article  CAS  Google Scholar 

  15. L. Lekha, K. K. Raja, G. Rajagopal, and D. Easwaramoorthy (2014). J. Mol. Struct. 1056–1057, 307.

    Article  Google Scholar 

  16. R. Gao, W. H. Sun, and C. Redshaw (2013). Catal. Sci. Technol. 3, 1172.

    Article  CAS  Google Scholar 

  17. C. G. Efthymiou, L. Cunha-Silva, S. P. Perlepes, E. K. Brechin, R. Inglis, M. Evangelisti, and C. Papatriantafyllopoulou (2016). Dalton Trans. 45, 17409.

    Article  CAS  Google Scholar 

  18. G. M. Sheldrick SHELXS-97 and SHELXL-97, Program for X-ray Crystal Structure Solution (University of Göttingen, Göttingen, Germany, 1997).

    Google Scholar 

  19. N. Hoshino, T. Ito, M. Nihei, and H. Oshio (2002). Chem. Lett. 31, 844.

    Article  Google Scholar 

  20. T. K. Karmakar, S. K. Chandra, J. Ribas, G. Mostafa, T. H. Luc, and B. K. Ghosh (2002). Chem. Commun. 20, 2364.

    Article  Google Scholar 

  21. M. S. E. Fallah, E. Rentschler, A. Caneschi, and D. Gatteschi (1996). Inorg. Chim. Acta 247, 231.

    Article  Google Scholar 

  22. E. C. Yang, W. Wernsdorfer, S. Hill, R. S. Edwards, M. Nakano, S. Maccagnano, L. N. Zakharov, A. L. Rheingold, G. Christou, and D. N. Hendrickson (2003). Polyhedron 22, 1727.

    Article  CAS  Google Scholar 

  23. M. Moragues-Cánovas, M. Helliwell, L. Ricard, E. Rivière, W. Wernsdorfer, E. Brechin, and T. Mallah (2004). Eur. J. Inorg. Chem. 11, 2219.

    Article  Google Scholar 

  24. A. Sieber, C. Boskovic, R. Bircher, O. Waldmann, S. T. Ochsenbein, G. Chaboussant, H. U. Güdel, N. Kirchner, J. van Slageren, W. Wernsdorfer, A. Neels, H. Stoeckli-Evans, S. Janssen, F. Juranyi, and H. Mutka (2005). Inorg. Chem. 44, 4315.

    Article  CAS  Google Scholar 

  25. A. Das, F. J. Klinke, S. Demeshko, S. Meyer, S. Dechert, and F. Meyer (2012). Inorg. Chem. 51, 8141.

    Article  CAS  Google Scholar 

  26. S. H. Zhang, Y. D. Zhang, H. H. Zou, J. J. Guo, H. P. Li, Y. Song, and H. Liang (2013). Inorg. Chim. Acta 396, 119.

    Article  CAS  Google Scholar 

  27. Q. L. Zhang, Z. L. Wu, H. Xu, B. Zhai, Y. F. Wang, G. W. Feng, and Y. L. Huang (2016). Z. Anorg. Allg. Chem. 642, 414.

    Article  CAS  Google Scholar 

  28. T. Li, Y. Wang, L. Qin, T. Han, Y. S. Ding, Y. Q. Hu, and Y. Z. Zheng (2016). Dalton Trans. 45, 10798.

    Article  CAS  Google Scholar 

  29. N. F. Chilton, R. P. Anderson, L. D. Turner, A. Soncini, and K. S. Murray (2013). J. Comput. Chem. 34, 1164.

    Article  CAS  Google Scholar 

  30. P. S. Perlepe, A. A. Athanasopoulou, K. I. Alexopoulou, C. P. Raptopoulou, V. Psycharis, A. Escuer, S. P. Perlepes, and T. C. Stamatatos (2014). Dalton Trans. 44, 16605.

    Article  Google Scholar 

  31. L. Yang, S. H. Zhang, W. Wang, J. J. Guo, Q. P. Huang, R. X. Zhao, C. L. Zhang, and G. Muller (2014). Polyhedron 74, 49.

    Article  CAS  Google Scholar 

  32. M. Cindrić, G. Pavlović, D. Pajić, K. Zadro, D. Cinčić, T. Hrenar, E. Lekšić, A. B. P. Prieto, P. Lazić, and D. Š. Jung (2016). New J. Chem. 40, 6604.

    Article  Google Scholar 

  33. R. Herchel, I. Nemec, M. Machata, and Z. Trávníček (2016). Dalton Trans. 45, 18622.

    Article  CAS  Google Scholar 

  34. H. Y. Zhang, Y. Li, W. Wang, X. Zhang, J. M. Wang, and S. H. Zhang (2016). J. Coord. Chem. 69, 1938.

    Article  CAS  Google Scholar 

  35. J. Wang, C. Feng, C. M. Ge, S. Zhang, and H. Hai (2016). J Clust. Sci. 27, 2001.

    Article  CAS  Google Scholar 

  36. S. Petit, P. Neugebauer, G. Pilet, G. Chastanet, A. L. Barra, A. B. Antunes, W. Wernsdorfer, and Dominique Luneau (2012). Inorg. Chem. 51, 6645.

    Article  CAS  Google Scholar 

  37. J. A. Mydosh Spin Glasses: An Experimental Introduction (Taylor and Francis, London, 1993).

    Google Scholar 

Download references

Acknowledgements

This work was supported by the National Natural Science Foundation of China (21601004) and Natural Science Foundation of the Higher Education Institutions of Anhui Province (KJ2016A485, KJ2017A242).

Author information

Authors and Affiliations

  1. Department of Chemistry, Bengbu Medical College, Bengbu, 233030, Anhui, People’s Republic of China

    Lili Liang, Wenge Li, Yaoyao Sun, Min Li, Xia Xu, Tao Wu & Shihang Xie

  2. State Key Laboratory of Coordination Chemistry, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing, 210093, People’s Republic of China

    Lili Liang

Authors
  1. Lili Liang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Wenge Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yaoyao Sun
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Min Li
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Xia Xu
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Tao Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Shihang Xie
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Wenge Li.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Liang, L., Li, W., Sun, Y. et al. A Cuboidal Tetranuclear Nickel Cluster Based on O,O,N-Tridentate Schiff Base: Synthesis, Structure and Magnetic Properties. J Clust Sci 29, 151–157 (2018). https://doi.org/10.1007/s10876-017-1321-y

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10876-017-1321-y

Keywords

Search

Navigation