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One Novel 3D Supramolecular Network Based on Dicobalt-Carboxylate Secondary Building Units with Polycarboxylate Ligands 1, 2, 3, 4-Butanetetracarboxylic Acid

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Abstract

A novel cobalt–carboxylate framework constructed from secondary building units (SBUs), {[Co16(btca)8(H2O)40]·16H2O}n (1) (H4btca = 1,2,3,4-butanetetracarboxylic acid) has been hydrothermally synthesized and characterized by techniques of single-crystal X-ray diffraction analyses, elemental analyses, infrared spectra, powder X-ray diffraction and thermogravimetric analyses. The complex exhibits 2D 4-connected sql net with (44 × 62) topology symbol built from [Co2(COO)4(H2O)5] SBUs and is further extended into a 3D supramolecular architecture via strong O–H···O hydrogen bonds. Moreover, the magnetic measurements indicate complex 1 exhibit antiferromagnetic behavior.

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Acknowledgements

This work was financially supported by the Scientific Research Foundation for the Introduced Talents of Kunming University of Science and Technology (No. KKSY201507026), the Analysis Testing Fund of Kunming University of Science and Technology (Nos. 2017T20040109, 2017M20152111048), the Joint Fund of National Natural Science Foundation of China and Yunnan (Grant No. U1502273), and the State Key Laboratory of Complex Nonferrous Metal Resources Clean Utilization, Kunming 650093 (Grant No. CNMRCUKF1606).

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Authors and Affiliations

  1. Faculty of Science, Kunming University of Science and Technology, Kunming, 650500, China

    Xiaofei Xue, Yuqi Liu, Yubo Xing, Xinying Wang & Wei Li

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  1. Xiaofei Xue
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  2. Yuqi Liu
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  3. Yubo Xing
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  4. Xinying Wang
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  5. Wei Li
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Correspondence to Yuqi Liu or Wei Li.

Electronic supplementary material

Below is the link to the electronic supplementary material.

10876_2017_1316_MOESM1_ESM.docx

Supplementary material CCDC 1559900 contains the supplementary crystallographic data for complex 1. The data can be obtained free of charge viahttp://www.ccdc.cam.ac.uk/data_request/cif

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Xue, X., Liu, Y., Xing, Y. et al. One Novel 3D Supramolecular Network Based on Dicobalt-Carboxylate Secondary Building Units with Polycarboxylate Ligands 1, 2, 3, 4-Butanetetracarboxylic Acid. J Clust Sci 29, 121–127 (2018). https://doi.org/10.1007/s10876-017-1316-8

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  • DOI: https://doi.org/10.1007/s10876-017-1316-8

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