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Synthesis, Structure, and Magnetic Properties of a Twist Linear Tetranuclear Co III2 Ln III2 Complexes

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Abstract

A series of twist linear tetranuclear 3d–4f Co III2 Ln III2 [Ln = Gd (1), Tb (2), Dy (3), Ho (4), Er (5)] complexes have been prepared under solvothermal conditions and structurally characterized with Schiff-base ligand 2-(((2-hydroxy-3-methoxyphenyl)methylene)amino)-2-(hydroxymethyl)-1,3-propanediol (H4L). The two central Co ions are linked by two alkoxyl oxygen atoms, and one Ln ion lying above and the other below the Co–Co dimer, form a twist linear array. The magnetic susceptibility studies reveal antiferromagnetic or ferromagnetic behaviour, whilst dynamic magnetic studies indicate no slow magnetic relaxation for these complexes.

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Acknowledgements

This work was supported by the National Natural Science Foundation of China (Nos. 21601038, 51572050, 21401112, 21461004), Guangxi Natural Science Foundation (Nos. 2015GXNSFDA139007 and 2016GXNSFAA380085), and Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials (EMFM20162107).

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Author notes

  1. Han-Bai Quan and Liang-Bing Sheng have contributed equally to this work.

Authors and Affiliations

  1. State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry and Pharmacy, Guangxi Normal University, Guilin, 541004, People’s Republic of China

    Han-Bai Quan, Liang-Bing Sheng, Hua-Hong Zou, Zi-Yuan Liu, Dong-Cheng Liu, Man-Sheng Chen & Fu-Pei Liang

  2. College of Chemistry and Pharmaceutical Engineering, Nanyang Normal University, Nanyang, 473061, People’s Republic of China

    Bo Li

  3. Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin, 541004, People’s Republic of China

    Fu-Pei Liang

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  1. Han-Bai Quan
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Correspondence to Hua-Hong Zou, Bo Li or Fu-Pei Liang.

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Quan, HB., Sheng, LB., Zou, HH. et al. Synthesis, Structure, and Magnetic Properties of a Twist Linear Tetranuclear Co III2 Ln III2 Complexes. J Clust Sci 29, 75–81 (2018). https://doi.org/10.1007/s10876-017-1303-0

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  • DOI: https://doi.org/10.1007/s10876-017-1303-0

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