Journal of Cluster Science

, Volume 28, Issue 4, pp 2185–2203 | Cite as

Three Luminescent Copper(I) Iodide Clusters with Phosphine Ligands: Synthesis, Structure Characterization, Properties and TD-DFT Calculations

  • Rong-Er Shou
  • Wen-Xiang Chai
  • Li Song
  • Lai-Shun Qin
  • Hong-Sheng Shi
  • Tian-Gen Wang
Original Paper

Abstract

Three new luminescent copper(I) iodide complexes with their respective phosphine ligands, namely [Cu(μ 2-I)(o-Anisyl3P)]2·CH3CN (1), [Cu(μ 3-I)(m-Anisyl3P)]4 (2) and [Cu(μ 3-I)(p-Anisyl3P)]4 (3) (Anisyl = methoxyphenyl), have been synthesized by reacting CuI with the phosphine ligand in 1:1 molar ratio. All complexes were characterized by spectroscopic analysis (IR, UV–Vis), elemental analysis, and photoluminescence study. Single-crystal X-ray diffraction revealed that complex 1 is a di-nuclear cluster structure, while both of complex 2 and 3 are cubic-like tetra-nuclear cluster structures. All complexes exhibit intense blue-green luminescence in the solid state. The excited states of all complexes have been assigned as halide-to-ligand charge transfer state mixed with metal-to-ligand charge transfer character based on the TD-DFT calculations. The complex 2 and 3 are thermally stable according to thermogravimetric analysis so that they are suitable for applying in luminescent devices.

Keywords

Copper(I) iodide clusters Phosphine ligand Crystal structure Phosphorescence TD-DFT 

Notes

Acknowledgements

The authors are grateful for financial support from the Science and Technology Project of Zhejiang Province (Project No. 2015C33047), and Zhejiang Provincial Natural Science Foundation of China (No. LY16B030009).

Supplementary material

10876_2017_1218_MOESM1_ESM.doc (2.2 mb)
Supplementary material 1 (DOC 2254 kb)

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Copyright information

© Springer Science+Business Media New York 2017

Authors and Affiliations

  • Rong-Er Shou
    • 1
  • Wen-Xiang Chai
    • 1
  • Li Song
    • 2
  • Lai-Shun Qin
    • 1
  • Hong-Sheng Shi
    • 1
  • Tian-Gen Wang
    • 1
  1. 1.College of Materials Science and EngineeringChina Jiliang UniversityHangzhouPeople’s Republic of China
  2. 2.Department of ChemistryZhejiang Sci-Tech UniversityHangzhouPeople’s Republic of China

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