Journal of Cluster Science

, Volume 28, Issue 4, pp 2239–2252 | Cite as

Synthesis, Structural Characterization, Hirshfeld Surface and Antioxidant Activity Analysis of a Novel Organic Cation Antimonate Complex

  • Ikram Lahbib
  • Arto Valkonen
  • Mohamed Rzaigui
  • Wajda Smirani
Original Paper
  • 90 Downloads

Abstract

A new organic–inorganic hybrid material of formula (C10H15N2)7 Sb2Cl10 Sb2Cl9 (SbCl5)2 SbCl4 2Cl·7H2O was synthesized and characterized by an X-ray diffraction analysis. It crystallizes in the triclinic system with the P\(\bar{1}\) space group and the following unit cell parameters a = 11.8127(3) Å, b = 15.7557(4) Å, c = 35.4511(8) Å, α = 89.409(1)°, β = 84.04(1)°, γ = 71.116(1)°, Z = 2 and V = 6207.3(3) Å3. The examination of the structure shows that the two dimensional frameworks are produced by O–H Cl, N–H⋯Cl and N–H⋯O hydrogen bonding. In addition, the most important features of crystal packing and intermolecular interactions in the title complex were quantified via Hirshfeld surface analysis. Differential scanning calorimetry has revealed a dehydration phenomenon at around 348 K. The investigation of the antioxidant activity of the title compound was carried out using the 2,2-diphenyl-1-picrylhydrazyl and ferrous iron chelating methods.

Keywords

Antimonates Crystal structure Hirshfeld surface Photoluminescence Antioxidant activity 

Notes

Acknowledgements

The authors gratefully acknowledge the support of the Tunisian Ministry of Higher Education and Scientific Research.

Supplementary material

10876_2017_1217_MOESM1_ESM.docx (1.7 mb)
Supplementary material 1 (DOCX 1765 kb)

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Copyright information

© Springer Science+Business Media New York 2017

Authors and Affiliations

  • Ikram Lahbib
    • 1
  • Arto Valkonen
    • 2
  • Mohamed Rzaigui
    • 1
  • Wajda Smirani
    • 1
  1. 1.Laboratoire de Chimie des Matériaux, Faculté des Sciences of BizerteUniversité de CarthageZarzounaTunisia
  2. 2.Department of Chemistry and BioengineeringTampere University of TechnologyTampereFinland

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