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A New 2-D Inorganic–Organic Hybrid Polyoxometalate Based on Mono-Cu-Substituted [CuSiW11O39] 6n− n Chains and [Cu(en)2]2+ Bridges

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Abstract

A new organic–inorganic hybrid polyoxometalate H2[Cu(en)2(H2O)]2[Cu(en)2]{[Cu(en)2]3 (CuSiW11O39)2}·6H2O (1) (en = ethylenediamine) have been hydrothermally synthesized and characterized by IR spectrum, thermogravimetric analysis, power X-ray diffraction and single-crystal X-ray diffraction. Crystal data for 1: monoclinic, P21/c, a = 18.8077(3) Å, b = 23.0703(5) Å, c = 26.0723(6) Å, β = 96.438(2)°, Z = 4. Single-crystal X-ray diffraction analysis revealed that 1 exhibits a 2-dimensional network constructed from mono-Cu-substituted [CuSiW11O39] 6n− n chains and [Cu(en)2]2+ bridges.

Graphical Abstract

A new organic–inorganic hybrid polyoxometalate H2[Cu(en)2(H2O)]2[Cu(en)2]{[Cu(en)2]3(CuSiW11O39)2}·6H2O (1) (en = ethylenediamine) have been hydrothermally synthesized and characterized, which exhibits a 2-dimensional network constructed from mono-Cu-substituted [CuSiW11O39] 6n− n chains and [Cu(en)2]2+ bridges.

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Acknowledgements

This work was supported by the NSFC (Grants 21571016, 91122028 and 50872133), the NSFC for Distinguished Young Scholars of China (Grant 20725101).

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Authors and Affiliations

  1. MOE Key Laboratory of Cluster Science, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing, 100081, China

    Peng-Chao Ci, Zhong Zhang, Bai-Feng Yang & Guo-Yu Yang

  2. College of Chemistry, Fuzhou University, Fuzhou, 350116, Fujian, China

    Xin-Xiong Li

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  1. Peng-Chao Ci
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  2. Zhong Zhang
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Correspondence to Xin-Xiong Li or Guo-Yu Yang.

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Ci, PC., Zhang, Z., Yang, BF. et al. A New 2-D Inorganic–Organic Hybrid Polyoxometalate Based on Mono-Cu-Substituted [CuSiW11O39] 6n− n Chains and [Cu(en)2]2+ Bridges. J Clust Sci 28, 1249–1257 (2017). https://doi.org/10.1007/s10876-016-1138-0

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  • DOI: https://doi.org/10.1007/s10876-016-1138-0

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