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Crystal Structures and Photoluminescence of Two Inorganic–Organic Hybrids of Anderson Anions

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Abstract

Two supramolecular compounds (Hbipy)2[Cr(OH)6Mo6O18H](bipy) (1) and (Hbipy)3[Al(OH)6Mo6O18]·3H2O (2) were synthesized and their crystal structures were analyzed with x-ray diffraction technique. In 1 the Anderson anion with six hydroxyl groups forms six hydrogen bonds with bipy molecules, forming a supramolecular layer, the layers are linked by hydrogen bonds between anions. In 2 the Anderson anion with three hydroxyl groups and terminal/bridging oxygen atoms forms six hydrogen bonds with bipy molecules, and lattice water molecules and the anions form also hydrogen bonds, constructing a supramolecular architecture. The intensive emission in 650–740 nm of 1 is attributed to R-lines of Cr3+ and the high intensity may be caused by energy transfer of bipy molecules through hydrogen bonds. In contrast, 2 gives only the π* → π emission of bipy molecules at 460 nm.

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Authors and Affiliations

  1. Key Laboratory of Polyoxometalates Science of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun, 130024, China

    Xiao-Min Li, Yan Guo, Tian Shi & Ya-Guang Chen

  2. Department of Chemistry, Yili Normal University, Yining, Xingjiang, 835000, China

    Xiao-Min Li

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  1. Xiao-Min Li
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  2. Yan Guo
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  3. Tian Shi
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  4. Ya-Guang Chen
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Correspondence to Ya-Guang Chen.

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Li, XM., Guo, Y., Shi, T. et al. Crystal Structures and Photoluminescence of Two Inorganic–Organic Hybrids of Anderson Anions. J Clust Sci 27, 1913–1922 (2016). https://doi.org/10.1007/s10876-016-1072-1

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