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Syntheses, Crystal Structure and Property of a Heterometallic Heptanuclear Cluster

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Abstract

A novel heterometallic heptanuclear cluster [(hmbame)2 \(Co_{4}^{III}\)CoIINa2(N3)8 (OH)2]·4H2O (1), (H3hmbame is 6,6′-((1Z,1′E)-(((3-ethoxy-2-hydroxyphenyl) methylene)bis(azanylylidene))bis(methanylylidene))bis (2-ethoxy phenol)) was synthesized by in situ reaction. Complex 1 was structurally characterized by elemental analysis, IR, UV–Vis spectroscopy and single crystal X-ray diffraction. Complex 1 crystallizes in the triclinic space group Pī, showing a disc-like configuration. Luminescent property of 1 has been studied. The results indicate that it may be good candidate for useful photoactive material.

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Scheme 1
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Scheme 2
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Acknowledgments

This work is financially supported by the Nature Science Foundation of Guangxi Province of China (No. 2015GXNSFAA139031); Program for the scientific research and technology development plan of Guilin (No.20150133-5) and Program of the first session backbone teacher of Guangxi of China.

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Authors and Affiliations

  1. School of Geosciences and Info-Physics, Central South University, Changsha, 410083, China

    Zheng-Guang Hu & Song-Ling Chen

  2. College of Chemistry and Bioengineering, (Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, Collaborative Innovation Center for Exploration of Hidden Nonferrous Metal Deposits and Development of New Materials in Guangxi), Guilin University of Technology, Guilin, 541004, China

    Zheng-Guang Hu, Ru-Xia Zhao & Shu-Hua Zhang

  3. Shandong Drug and Food Vocational College, Wei-Hai, 264200, China

    Ru-Xia Zhao

  4. Chinalco Guangxi Nonferrous Rare Earth Development Co., LTD, Nanning, 530022, China

    Zheng-Guang Hu

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Correspondence to Shu-Hua Zhang or Song-Ling Chen.

Electronic supplementary material

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10876_2016_1069_MOESM1_ESM.doc

Supplementary material 1 (DOC 1932 kb) Supplementary Information Crystallographic data (including structure factors) for the structure in this paper has been deposited with the Cambridge Crystallographic Data Centre as supplementary publication CCDC 1478652. Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: 44 1223 336033, e-mail: deposit@ccdc.cam.ac.uk). Electronic supplementary information (ESI) available:[The reaction mechanism of H3hmbame (Scheme S1); Packing drawing of 1 (Figure S1); The IR of 1 (Figure S2)]

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Hu, ZG., Zhao, RX., Zhang, SH. et al. Syntheses, Crystal Structure and Property of a Heterometallic Heptanuclear Cluster. J Clust Sci 27, 1933–1943 (2016). https://doi.org/10.1007/s10876-016-1069-9

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