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Synthesis, Crystal Structures and Properties of a Series of Lanthanide Adipates [Ln 2(ad)3(H2O)4] (Ln = Y3+, Ho3+, Er3+, Tm3+)

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Abstract

A series of lanthanides adipates [Ln 2(ad)3(H2O)4] [Ln = Y3+ (1), Ho3+ (2), Er3+ (3), Tm3+ (4); ad = adipate] have been hydrothermally synthesized and structurally characterized by elemental analysis, X-ray diffraction, thermogravimetric analysis, UV/Vis and IR spectroscopy. Compounds 1–4 are isostructural and exhibit 2-D polymeric layers constructed by Ln 3+ ions bridged via the carboxylate groups of adipate ligands in two binding modes. The magnetic properties of both 2 and 4 are investigated and their thermal behaviours are also discussed.

Graphical Abstract

The Ln 3+ ions (Ln = Y3+, Ho3+, Er3+, Tm3+) bridged by the carboxylate groups of adipate ligands form 2-D polymeric layers.

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Acknowledgments

This work was supported by the NNSF of china (Nos. 21671029 and 21271143), the NSF of Chongqing municipality (Nos. cstc2014jcyjA50002, cstc2015jcyjBX0117), and Program for Excellent Talents in Chongqing Higher Education Institutions. The authors are also grateful to Chongqing Normal University for financial support (Nos. 14CSLJ02, 13XLZ07), graduate innovative research projects of Chongqing municipality (CYS16147) and the Innovative Training Program of University Student (No. 201510637018).

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Authors and Affiliations

  1. College of Chemistry, Chongqing Normal University, Chongqing, 401331, China

    Xiao-Feng Tan, Jian Zhou, Qiuling Tang, Tingting Jiang & Xiaoyan Zhang

  2. State Key Laboratory for Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry & Pharmacy of Guangxi Normal University, Guilin, 541004, China

    Hua-Hong Zou

  3. College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, 325035, China

    Hong-Ping Xiao

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  1. Xiao-Feng Tan
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  2. Jian Zhou
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  3. Hua-Hong Zou
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  4. Hong-Ping Xiao
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  5. Qiuling Tang
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Correspondence to Jian Zhou or Hua-Hong Zou.

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Tan, XF., Zhou, J., Zou, HH. et al. Synthesis, Crystal Structures and Properties of a Series of Lanthanide Adipates [Ln 2(ad)3(H2O)4] (Ln = Y3+, Ho3+, Er3+, Tm3+). J Clust Sci 27, 2025–2033 (2016). https://doi.org/10.1007/s10876-016-1066-z

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  • DOI: https://doi.org/10.1007/s10876-016-1066-z

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