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Two New Cubane-Type Tetranuclear Compounds of Copper(II), Nickel(II) Derived from Reduced Schiff Base Ligand: Syntheses, Structures and Magnetic Properties

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Abstract

Two tetranuclear complexes, [M(H3L)]4·X (1, M = Cu, X = 4,4′-dpdo; 2, M = Ni, X = DMF, H5L = 2-[(3,5-dibromo-2-hydroxybenzyl) amino]-2-(hydroxymethyl)propane-1,3-diol, 4,4′-dpdo is 4,4′-bipyridine-N,N′-dioxide, DMF = N,N′-dimethyl formamide), have been synthesized and characterized by elemental analysis, IR and X-ray single-crystal diffraction. Compound 1 features a centrosymmetric tetranuclear copper cluster which further constructed a 1D chain through a tetra-acceptor hydrogen bonds of 4,4′-dpdo molecule. Compound 2 having a P21 /n space group also exhibits a tetranuclear nickel cluster with a cubane topology in which the central Ni(II) ion and oxygen atoms from H3L2− occupy the alternate vertices of the cube. Magnetic properties of 1 and 2 in the 2–300 K have also been discussed. The tetranuclear cubanes cores display dominant ferromagnetic interactions.

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Acknowledgments

This work was supported by the National Nature Science Foundation of China (No. 21161006), the Nature Science Foundation of Guangxi Province of China (No. 2015GXNSFAA139031); Program for the scientific research and technology development plan of Guilin (No. 20150133-5); Guangxi Key Laboratory of Environmental Pollution Control Theory and Technology; the Innovation Project of Guangxi Graduate Education (SS201606).

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Authors and Affiliations

  1. College of Chemistry and Bioengineering (Guangxi Key Laboratory of Electrochemical and Magneto-chemical Functional Materials, Collaborative Innovation Center for Exploration of Hidden Nonferrous Metal Deposits and Development of New Materials in Guangxi), Guilin University of Technology, Guilin, 541004, China

    Jiming Wang, Chao Feng, Cheng Min Ge, Shuhua Zhang & Hong Hai

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  1. Jiming Wang
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  2. Chao Feng
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  3. Cheng Min Ge
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  4. Shuhua Zhang
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Correspondence to Shuhua Zhang or Hong Hai.

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Wang, J., Feng, C., Ge, C.M. et al. Two New Cubane-Type Tetranuclear Compounds of Copper(II), Nickel(II) Derived from Reduced Schiff Base Ligand: Syntheses, Structures and Magnetic Properties. J Clust Sci 27, 2001–2011 (2016). https://doi.org/10.1007/s10876-016-1064-1

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