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A Luminescent Three-Dimensional Coordination Polymer Based on Cu(I) Halide Clusters Showing Dia Topology with 8-Fold Interpenetration

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Abstract

One interesting copper(I) halide-based coordination polymer with a formula of [Cu4(Br)4(bib)2]n (1) (bib = 1,4-bis(imidazol-2-methyl)butane) has been prepared by solvothermal method, and characterized by X-ray single crystal diffraction, elemental analyses, IR and TGA. Structure analyses reveal that the compound is constructed of copper(I) halide clusters and flexible bib ligands, which features a 8-fold interpenetrated 3D framework with 4-connected extended dia topology. Furthermore, the compound exhibits high thermal stability and intense fluorescent emission, and can be explored for potential red luminescent materials.

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Acknowledgments

This work was supported by the National Natural Science Foundation of China (21401097) and the Foundation for University Young Key Teacher by Henan Province of China (2014GGJS-116).

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Authors and Affiliations

  1. College of Food and Drug, Luoyang Normal University, Luoyang, 471934, Henan, China

    Li-Ping Xue

  2. Department of Chemistry, Zhengzhou University, Zhengzhou, 450052, China

    Jing-Jing Tao

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  1. Li-Ping Xue
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  2. Jing-Jing Tao
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Correspondence to Li-Ping Xue.

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Xue, LP., Tao, JJ. A Luminescent Three-Dimensional Coordination Polymer Based on Cu(I) Halide Clusters Showing Dia Topology with 8-Fold Interpenetration. J Clust Sci 27, 1729–1736 (2016). https://doi.org/10.1007/s10876-016-1036-5

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