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Solvothermal Synthesis, Structure and Magnetic Properties of a Novel Heterometallic Cluster with 2-Ethoxy-6-methyliminomethyl-phenol

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Abstract

The reaction of Co(ClO4)2·6H2O with 3-ethoxy-2-hydrogxy-benzaldehyde, methyamine and KOH in DMF solution, under solvothermal conditions, leads to the formation of the heterotetrametallic cluster {[Co3K(emimp)4(DCA)2]·ClO4}6·(H2O) (1) (Hemimp = 2-ethoxy-6- methyliminomethyl-phenol, HDCA = Dimethyl-carbamic acid). Compound 1 displays dominant anti-ferromagnetic interactions through μ 1,1,3,3-DCA and μ 2-O bridging mode. HDCA was synthesized by in situ reaction and DMF was oxidized.

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References

  1. E. A. Suturina, D. Maganas, E. Bill, M. Atanasov, and F. Neese (2015). Inorg. Chem. 54, (20), 9948.

    Article  CAS  Google Scholar 

  2. S. H. Zhang, Q. P. Huang, H. Y. Zhang, G. Li, Z. Liu, Y. Li, and H. Liang (2014). J. Coord. Chem. 67, (19), 3155.

    Article  CAS  Google Scholar 

  3. F. Pointillart, B. L. Guennic, O. Cador, O. Maury, and L. Ouahab (2015). Acc. Chem. Res. 48, (11), 2834.

    Article  CAS  Google Scholar 

  4. A. Vinslava, A. J. Tasiopoulos, W. Wernsdorfer, K. A. Abboud, and G. Christou (2016). Inorg. Chem. doi:10.1021/acs.inorgchem.5b02790.

    Google Scholar 

  5. S. H. Zhang, M. H. Zeng, and H. Liang (2008). Chin. J. Sruct. Chem. 27, 785.

    Google Scholar 

  6. S.-H. Zhang, M. F. Tang, and C. M. Ge (2009). Z. Anorg. Allg. Chem. 635, 1442.

    Article  CAS  Google Scholar 

  7. C.-M. Ge, S. H. Zhang, C. Feng, Y. G. Wang, and W. Li (2011). Z. Anorg. Allg. Chem. 637, 112.

    Article  CAS  Google Scholar 

  8. S. H. Zhang, G. Li, H. Y. Zhang, and H. P. Li (2015). Z. Kristallogr. 230, 479.

    CAS  Google Scholar 

  9. Q. P. Huang, G. Li, H. Y. Zhang, S.-H. Zhang, and H. P. Li (2014). Z. Anorg. Allg. Chem. 640, 1403.

    Article  CAS  Google Scholar 

  10. L. Yang, Q. P. Huang, C. L. Zhang, R. X. Zhao, and S. H. Zhang (2014). Supramol. Chem. 26, 81.

    Article  CAS  Google Scholar 

  11. Q. P. Huang, S. H. Zhang, H. Y. Zhang, G. Li, and M. C. Wu (2014). J. Cluster Sci. 25, 1489.

    Article  CAS  Google Scholar 

  12. S. H. Zhang, R. X. Zhao, G. Li, H. Y. Zhang, C. L. Zhang, and G. Muller (2014). RSC Adv. 4, 54837.

    Article  CAS  Google Scholar 

  13. S. H. Zhang, N. Li, C. M. Ge, C. Feng, and L. F. Ma (2011). Dalton Trans. 40, 3000.

    Article  CAS  Google Scholar 

  14. H. Li, Z.-J. Yao, D. Liu, and G.-X. Jin (2015). Coord. Chem. Rev. 293–294, 139.

    Article  Google Scholar 

  15. K. Liu, W. Shi, and P. Cheng (2015). Coord. Chem. Rev. 289–290, 74.

    Article  Google Scholar 

  16. Bruker (2001). SMART (Version 5.0) and SAINT (Version 6.45). Bruker AXS Inc., Madison, Wisconsin, USA.

  17. G. M. Sheldrick (2008). Acta Cryst. A64, 112.

    Article  Google Scholar 

  18. G. M. Sheldrick SADABS (University of Göttingen, Göttingen, 1996).

    Google Scholar 

  19. S. G. Baca, T. Mikosch, M. Speldrich, J. van Leusen, A. Ellem, and P. Kogerler (2013). Inorg. Chem. 52, 4154.

    Article  CAS  Google Scholar 

  20. C. E. Anson, W. Klopper, J. S. Li, L. Ponikiewski, and A. Rothenberger (2006). Chem. Eur. J. 12, 2032.

    Article  CAS  Google Scholar 

  21. S. H. Zhang, Y. M. Jiang, Y. Xiao, and Z. Y. Zhou (2003). Chin. J. Inorg. Chem. 19, 517.

    CAS  Google Scholar 

  22. H. H. Zou, S. H. Zhang, Y. Xiao, C. Feng, and Y. G. Wang (2011). Struct. Chem. 22, 135.

    Article  CAS  Google Scholar 

  23. M. J. Hossain, M. Yamasaki, M. Mikuriya, A. Kuribayashi, and H. Sakiyama (2002). Inorg. Chem. 41, 4058.

    Article  CAS  Google Scholar 

  24. G. Li, W. Wang, S. H. Zhang, H. Y. Zhang, and F. Y. Chen (2014). J. Cluster Sci. 25, (6), 1589.

    Article  CAS  Google Scholar 

  25. Y. Xu, Y. X. Che, and J. M. Zheng (2013). Z. Anorg. Allg. Chem. 639, 784.

    Article  CAS  Google Scholar 

  26. L. Zhang, W. Li, J. Zhang, Z. J. Li, Y. Y. Qin, J. K. Cheng, and Y. G. Yao (2008). Inorg. Chem. Commun. 11, 279.

    Article  CAS  Google Scholar 

  27. J. G. Wang, N. Chai, S. C. Wang, L. F. Ma, and L. Y. Wang (2013). Inorg. Chem. Commun. 30, 143.

    Article  CAS  Google Scholar 

  28. S. Konar, E. Zangrando, M. G. B. Drew, J. Ribas, and N. R. Chaudhuri (2004). Dalton Trans. 33, 260.

    Article  Google Scholar 

  29. S. H. Zhang, Y. Song, H. Liang, and M. H. Zeng (2009). CrystEngComm 11, 865.

    Article  Google Scholar 

  30. S. H. Zhang, Y. M. Jiang, and Z.-M. Liu (2008). J. Coord. Chem. 61, 1927.

    Article  CAS  Google Scholar 

  31. S. H. Zhang, G. Li, H. Y. Zhang, and H. P. Li (2015). Z. Kristallogr. 2015, (230), 479.

    Google Scholar 

  32. M. Shebl (2014). Spectrochim. Acta A 117, 127.

    Article  CAS  Google Scholar 

  33. S. H. Zhang, R. X. Zhao, G. Li, H. Y. Zhang, Q. P. Huang, and F. P. Liang (2014). J. Solid State Chem. 220, 206.

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by the National Nature Science Foundation of China (No. 21161006), Guangdong Province Breakthrough Program in Key Areas between Guangdong and Hong Kong [No. 2012BZ100054]; The Science and Technique Innovation Foundation of Foshan City [grant number 2014HK100204]; Major Scientific Research Programs of Foshan University; the Nature Science Foundation of Guangxi Province of China (No. 2015GXNSFAA139031); Program for the scientific research and technology development plan of Guilin (No. 20150133-5) and Program of the first session backbone teacher of Guangxi of China.

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Authors and Affiliations

  1. School of Material Science and Energy Engineering, Foshan University, Foshan, 528000, Guangdong, People’s Republic of China

    Qian Jun Deng

  2. College of Chemistry and Bioengineering, (Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, Collaborative Innovation Center for Exploration of Hidden Nonferrous Metal Deposits and Development of New Materials in Guangxi), Guilin University of Technology, Guilin, 541004, People’s Republic of China

    Qian Jun Deng, Ru Xia Zhao, Jiming Wang, Chen Min Ge & Shu Hua Zhang

Authors
  1. Qian Jun Deng
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  2. Ru Xia Zhao
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  3. Jiming Wang
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  4. Chen Min Ge
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  5. Shu Hua Zhang
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Correspondence to Shu Hua Zhang.

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Deng, Q.J., Zhao, R.X., Wang, J. et al. Solvothermal Synthesis, Structure and Magnetic Properties of a Novel Heterometallic Cluster with 2-Ethoxy-6-methyliminomethyl-phenol. J Clust Sci 27, 1645–1653 (2016). https://doi.org/10.1007/s10876-016-1030-y

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  • DOI: https://doi.org/10.1007/s10876-016-1030-y

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