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Synthesis, Crystal Structure and Electrochemical Properties of A New 2D Network Containing Linear {ε-H2PMo V8 Mo VI4 O40Zn4}∞ Inorganic Chain

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Abstract

A new 2D network formulated as [TBA]3[H2PMo V8 Mo VI4 O40Zn4][C7H6(COO)2] (1) containing linear inorganic chain {ε-H2PMo V8 Mo VI4 O40Zn4}∞ has been synthesized and structurally characterized by FT-IR, thermal analysis, single crystal and powder X-ray diffraction. Compound 1 shows remarkable electrocatalytic activity towards bromate reduction, nitrite reduction and ascorbic acid oxidation. Moreover, the proton conduction behavior of 1 has also been investigated.

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References

  1. D.-Y. Du, J.-S. Qin, S.-L. Li, Z.-M. Su, and Y.-Q. Lan (2014). Chem. Soc. Rev. 43, 4615.

    Article  CAS  Google Scholar 

  2. S.-T. Zheng, J. Zhang, X.-X. Li, W.-H. Fang, and G.-Y. Yang (2010). J. Am. Chem. Soc. 132, 15102.

    Article  CAS  Google Scholar 

  3. R. Canioni, C. Roch-Marchal, F. Sécheresse, P. Horcajada, C. Serre, M. Hardi-Dan, G. Férey, J. M. Grenèche, F. Lefebvre, J. S. Chang, Y. K. Hwang, O. Lebedev, S. Turnerf, and G. V. Tendeloo (2011). J. Mater. Chem. 21, 1226.

    Article  CAS  Google Scholar 

  4. O.-A. Kholdeeva, N.-V. Maksimchuk, and G.-M. Maksimov (2010). Catal. Today 57, 107.

    Article  Google Scholar 

  5. C.-Y. Sun, S.-X. Liu, D.-D. Liang, K.-Z. Shao, Y.-H. Ren, and Z.-M. Su (2009). J. Am. Chem. Soc. 131, 1883.

    Article  CAS  Google Scholar 

  6. F.-J. Ma, S.-X. Liu, D.-D. Liang, G.-J. Ren, C.-D. Zhang, F. Wei, and Z.-M. Su (2010). Eur. J. Inorg. Chem. 24, 3756.

    Article  Google Scholar 

  7. F.-J. Ma, S.-X. Liu, C.-Y. Sun, D.-D. Liang, G.-J. Ren, F. Wei, Y.-G. Chen, and Z.-M. Su (2011). J. Am. Chem. Soc. 133, 4178.

    Article  CAS  Google Scholar 

  8. J. Song, Z. Luo, D. K. Britt, H. Furukawa, O. M. Yaghi, K. I. Hardcastle, and C. L. Hill (2011). J. Am. Chem. Soc. 133, 16839.

    Article  CAS  Google Scholar 

  9. S. Uchida and N. Mizuno (2007). Coord. Chem. Rev. 251, 2537.

    Article  CAS  Google Scholar 

  10. C.-J. Jiang, A. Lesbani, R. Kawamoto, S. Uchida, and N. Mizuno (2006). J. Am. Chem. Soc. 128, 14240.

    Article  CAS  Google Scholar 

  11. S. Uchida, M. Hashimoto, and N. Mizuno (2002). Angew. Chem. Int. Ed. 41, 2814.

    Article  CAS  Google Scholar 

  12. X.-Y. Zhao, D.-D. Liang, S.-X. Liu, C.-Y. Sun, R.-G. Cao, C.-Y. Gao, Y.-H. Ren, and Z.-M. Su (2008). Inorg. Chem. 47, 7133.

    Article  CAS  Google Scholar 

  13. C. Zou, Z.-J. Zhang, X. Xu, Q.-H. Gong, J. Li, and C.-D. Wu (2012). J. Am. Chem. Soc. 134, 87.

    Article  CAS  Google Scholar 

  14. A. Dolbecq, E. Dumas, C. R. Mayer, and P. Mialane (2010). Chem. Rev. 110, 6009.

    Article  CAS  Google Scholar 

  15. L. M. Rodriguez-Albelo, A. R. Ruiz-Salvador, A. Sampieri, D. W. Lewis, A. Gómez, B. Nohra, P. Mialane, J. Marrot, F. Sécheresse, C. Mellot-Draznieks, R. N. Biboum, B. Keita, L. Nadjo, and A. Dolbecq (2009). J. Am. Chem. Soc. 131, 16078.

    Article  Google Scholar 

  16. B. Nohra, H. E. Moll, L. M. Rodriguez-Albelo, P. Mialane, J. Marrot, C. Mellot-Draznieks, M. O’Keeffe, R. N. Biboum, J. Lemaire, B. Keita, L. Nadjo, and A. Dolbecq (2011). J. Am. Chem. Soc. 133, 13363.

    Article  CAS  Google Scholar 

  17. L. M. Rodriguez-Albelo, G. Rousseau, P. Mialane, J. Marrot, C. Mellot-Draznieks, A. R. Ruiz-Salvador, S.-W. Li, R.-J. Liu, G.-J. Zhang, B. Keita, and A. Dolbecq (2012). Dalton Trans. 41, 9989.

    Article  CAS  Google Scholar 

  18. J.-S. Qin, D.-Y. Du, W. Guan, X.-J. Bo, Y.-F. Li, L.-P. Guo, Z.-M. Su, Y.-Y. Wang, Y.-Q. Lan, and H.-C. Zhou (2015). J. Am. Chem. Soc. 137, 7169.

    Article  CAS  Google Scholar 

  19. S.-T. Zheng, D.-Q. Yuan, H.-P. Jia, J. Zhang, and G.-Y. Yang (2007). Chem. Commun. 18, 1858.

    Article  Google Scholar 

  20. H. Fu, C. Qin, Y. Lu, Z.-M. Zhang, Y.-G. Li, Z.-M. Su, W.-L. Li, and E.-B. Wang (2012). Angew. Chem. Int. Ed. 51, 7985.

    Article  CAS  Google Scholar 

  21. Q. Lan, J. Zhang, Z.-M. Zhang, Y. Lu, and E.-B. Wang (2013). Dalton Trans. 42, 16602.

    Article  CAS  Google Scholar 

  22. B.-X. Dong, L. Chen, S.-Y. Zhang, J. Ge, L. Song, H. Tian, Y.-L. Teng, and W.-L. Liu (2015). Dalton Trans. 44, 1435.

    Article  CAS  Google Scholar 

  23. B.-X. Dong, L. Chen, S.-Y. Zhang, Y.-C. Wu, H. Tian, J. Ge, L. Song, Y.-L. Teng, and W.-L. Liu (2015). J Clust Sci. doi:10.1007/s10876-015-0858-x.

  24. G. M. Sheldrick SHELXS 97, Program for Crystal Structure Solution (University of Göttingen, Göttingen, 1997).

    Google Scholar 

  25. G. M. Sheldrick SHELXL 97, Program for Crystal Structure Refinement (University of Göttingen, Göttingen, 1997).

    Google Scholar 

  26. A. L. Spek (2003). J. Appl. Crystallogr. 36, 7.

    Article  CAS  Google Scholar 

  27. C. Rocchiccioli-Deltcheff, M. Fournier, R. Franck, and R. Thouvenot (1983). Inorg. Chem. 22, 207.

    Article  CAS  Google Scholar 

  28. G. Rousseau, L. M. Rodriguez-Albelo, W. Salomon, P. Mialane, J. Marrot, F. Doungmene, I. Mbomekallé, P. de Oliveira, and A. Dolbecq (2015). Cryst. Growth. Des. 15, 449.

    Article  CAS  Google Scholar 

  29. Z.-F. Zhu, Y.-L. Bai, L.-L. Zhang, D.-F. Sun, J.-H. Fang, and S.-R. Zhu (2014). Chem. Commun. 50, 14674.

    Article  CAS  Google Scholar 

  30. M. Sadakane and E. Steckhan (1998). Chem. Rev. 98, 219.

    Article  CAS  Google Scholar 

  31. B. Keita and L. Nadjo (2007). J. Mol. Catal. A: Chem. 262, 190.

    Article  CAS  Google Scholar 

  32. T. Umemura and Y. Kurokawa (2006). Toxicology. 221, 154.

    Article  CAS  Google Scholar 

  33. Y. Kim and S. Shanmugam (2013). ACS Appl. Mater. Interfaces 5, 12197.

    Article  CAS  Google Scholar 

  34. D. M. Fernandes, A. D. S. Barbosa, J. Pires, S. S. Balula, L. Cunha-Silva, and C. Freire (2013). ACS Appl. Mater. Interfaces 5, 13382.

    Article  CAS  Google Scholar 

  35. C. L. Hill (1998). Chem. Rev. 98, 1.

    Article  CAS  Google Scholar 

  36. P. Ramaswamy, N. E. Wong, and G. K. H. Shimizu (2014). Chem. Soc. Rev. 43, 5913.

    Article  CAS  Google Scholar 

  37. D. E. Katsoulis (1998). Chem. Rev. 98, 359.

    Article  CAS  Google Scholar 

  38. A. Shigematsu, T. Yamada, and H. Kitagawa (2011). J. Am. Chem. Soc. 133, 2034.

    Article  CAS  Google Scholar 

  39. M.-L. Wei, X.-X. Wang, and X.-Y. Duan (2013). Chem. Eur. J. 19, 1607.

    Article  CAS  Google Scholar 

  40. M.-L. Wei, X.-X. Wang, J.-J. Sun, and X.-Y. Duan (2013). J. Solid State Chem. 202, 200.

    Article  CAS  Google Scholar 

  41. K. A. Mauritz and R. B. Moore (2004). Chem. Rev. 104, 4535.

    Article  CAS  Google Scholar 

  42. K. D. Kreuer (1996). Chem. Mater. 8, 610.

    Article  CAS  Google Scholar 

  43. J. Rozière and D. J. Jones (2003). Annu. Rev. Mater. Res. 33, 503.

    Article  Google Scholar 

  44. J. A. Hurd, R. Vaidhyanathan, V. Thangadurai, C. I. Ratcliffe, I. L. Moudrakovski, and G. K. H. Shimizu (2009). Nat. Chem. 1, 705.

    Article  CAS  Google Scholar 

  45. I. Honma, S. Nomura, and H. Nakajima (2001). J. Membr. Sci. 185, 83.

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work is financially supported by the NNSF of China (No. 21301152, 21371150, 21573192), Foundation from the Priority Academic Program Development of Jiangsu Higher Education Institutions.

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Authors and Affiliations

  1. Jiangsu Key Laboratory of Environmental Material and Environmental Engineering, Yangzhou University, Yangzhou, 225002, People’s Republic of China

    Bao-Xia Dong, Yi-Chen Wu & Chun-Bo Liu

  2. College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002, People’s Republic of China

    Bao-Xia Dong, Yi-Chen Wu, Hui Tian, Wen-Long Liu & Yun-Lei Teng

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  1. Bao-Xia Dong
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  2. Yi-Chen Wu
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  3. Hui Tian
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Correspondence to Bao-Xia Dong.

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Dong, BX., Wu, YC., Tian, H. et al. Synthesis, Crystal Structure and Electrochemical Properties of A New 2D Network Containing Linear {ε-H2PMo V8 Mo VI4 O40Zn4}∞ Inorganic Chain. J Clust Sci 27, 361–371 (2016). https://doi.org/10.1007/s10876-015-0935-1

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