Skip to main content
SpringerLink
Log in

Stabilization of Hexaborate Net with Mixed Co(II) Metal and Organic Cations: Synthesis, Rationale Characterization, Comparative Study and Enhancement of the Bioactivity

  • Original Paper
  • Published:
Journal of Cluster Science Aims and scope Submit manuscript

Abstract

A new Co(II)-hexaborate containing [Co{B6O7(OH)6}2]2− building blocks decorated with 1-cyanopiperazinium organic cation; (C5H11N3)[Co{B6O7(OH)6}2]·4H2O (1-CPCoB6) was synthesized from aqueous solution and the crystals were grown by the slow evaporation technique and characterized by means X-ray diffraction, IR UV–Vis and fluorescence spectroscopy measurements, elemental analysis and TDA-TG thermal analysis. The powder and single crystal XRD analysis revealed that the isolated pure crystals belong to the triclinic system. The structure exhibits interesting porous 3D-hydrogen-bonded network built by [Co{B6O7(OH)6}2]2−monomers. The cyanopiperazinium dications are filled in the free void channels of the inorganic framework and interact by means extensive hydrogen bonds. This hydrated mixed hexaborate thermally decomposed in multiple steps involving dehydration and release of organic cation leading to a novel unknown phase which undergoes crystallization. Moreover, the fluorescent and antimicrobial properties of 1-CPCoB6 have also been carried out, showing a red photoluminescence and a promising enhancement of biological activity of reported material in comparison with its parent reactants.

Graphical Abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6

Similar content being viewed by others

References

  1. W. R. Cook Jr and H. Jaffe (1957). Acta Crystallogr. 10, 705.

    Article  CAS  Google Scholar 

  2. M. Touboul and E. Betourne (1993). Solid State Ion. 63, 340.

    Article  Google Scholar 

  3. A. Garja (1968). Phys Status Solidi B 27, K93.

    Article  Google Scholar 

  4. V. P. Dotsenko, N. P. Efryshina, and I. V. Berezovskaya (1996). Mater. Lett. 28, 517.

    Article  CAS  Google Scholar 

  5. A. Akella and D. A. Keszler (1995). Mater. Res. Bull. 30, 105.

    Article  CAS  Google Scholar 

  6. S. Yang, G. Li, S. Tian, F. Liao, and J. Lin (2007). Cryst. Growth Des. 7, 1246.

    Article  CAS  Google Scholar 

  7. H.-X. Liu, Y.-X. Liang, and X. Jiang (2008). J. Solid State Chem. 181, 3243.

    Article  CAS  Google Scholar 

  8. P. Becker, P. Held, and L. Bohaty (2000). Cryst. Res. Technol. 35, 1251.

    Article  CAS  Google Scholar 

  9. B. V. Grinyov, M. F. Dubovik, and A. V. Tolmachev (2000). Semicond. Phys. Quantum Electron. Optoelectron. 3, (3), 410.

    CAS  Google Scholar 

  10. S. Natarajan, W. Klein, M. Panthöfer, L. V. Wüllen, and M. Jansen (2003). Z. Anorg. Allg. Chem. 629, 959.

    Article  CAS  Google Scholar 

  11. S. Yang, G. Li, J. Ju, Z. Yang, F. Liao, Y. Wang, and J. Lin (2008). Inorg. Chim. Acta 361, 2413.

    Article  CAS  Google Scholar 

  12. N. Jamai, M. Rzaigui, and S. Akriche Toumi (2014). Acta Cryst. E 70, m167.

    Article  CAS  Google Scholar 

  13. S. Akriche, A. Tliba, and M. Rzaigui (2014). J. Adv. Chem. 10, (3), 2377.

    Google Scholar 

  14. G. M. Sheldrick SHELXS/L-97, Programs for Crystal Structure Determination (University of Göttingen, Göttingen, 1997).

    Google Scholar 

  15. L. J. Farrugia, WINGX, A MS-Windows System Of Programs For Solving, Refining And Analysing Single Crystal X-ray Diffraction Data for Small Molecules (University of Glasgow, Glasgow, 2005).

    Google Scholar 

  16. K. Brandenburg and H. Putz, DIAMOND (Cryst. Impact. GbR., Bonn, 2005).

    Google Scholar 

  17. P. R. Murray, M.A. Pfaller, F.C. Tenover, E.J. Baron, and R.H. Yolken (eds), Manual of Clinical Microbiology (ASM Press, Washington, DC, 1999), pp. 1526–1543.

  18. National Committee for Clinical Laboratory Standards Performance Standards for Antimicrobial Susceptibility Testing; Wayne, Pennsylvania: NCCLS (1999) doc. M100-S9, 19(1), Table 2I.

  19. I. D. Brown, M. O’Keefe, and A. Navrotsky (eds), Structure and Bonding in Crystals, vol. 2, ch. 14 (Academic Press, New York, 1981), pp. 1–30.

  20. Y. Tao, Z. Lixia, X. Shuping, G. Shiyang, and Y. Kaibei (2003). J. Alloys Compd. 358, 87.

    Article  Google Scholar 

  21. Z. Liua, L. Li, J. Li, and M. Hu (2005). J. Alloys Compd. 394, 277.

    Article  Google Scholar 

  22. D. Kobashi, S. Kohara, J. Yamakawa, and A. Kawahara (1997). Acta Crystallogr. C 53, 1523.

    Article  Google Scholar 

  23. R. D. Shannon (1976). Acta Cryst. A32, 751.

    Article  CAS  Google Scholar 

  24. C. L. Christ and J. R. Clark (1977). Phys. Chem. Miner. 2, 59.

    Article  CAS  Google Scholar 

  25. E. L. Belokoneva (2005). Cryst. Rev. 11, (3), 151.

    Article  CAS  Google Scholar 

  26. A. Choudhury, S. Natarajan, and C. N. R. Rao (2000). J. Chem. Soc. Dalton Trans. 15, 2595–2598.

    Article  Google Scholar 

  27. S. Neeraj, C. N. R. Rao, and A. K. Cheetham (2004). J. Mater. Chem. 14, 814.

    Article  CAS  Google Scholar 

  28. D. Havlicek, J. Plocek, I. Nemec, R. Gyepes, and Z. Micka (2000). J. Solid State Chem. 150, 305.

    Article  CAS  Google Scholar 

  29. D. Havlicek, V. Chudoba, I. Nemec, I. Cısarova, and Z. Micka (2002). J. Mol. Struct. 606, 101.

    Article  CAS  Google Scholar 

  30. J. Plocek, D. Havlicek, I. Nemec, I. Cısarova, and Z. Micka (2003). J. Solid State Chem. 170, 308.

    Article  CAS  Google Scholar 

  31. Z. Lixia, Y. Tao, W. Jiang, and G. Shiyang (2007). Russ. J. Inorg. Chem. 52, 1786.

    Article  Google Scholar 

  32. J. Li, Sh P Xia, and Sh Y Gao (1995). Spectrochim. Acta 51, 519.

    Article  Google Scholar 

  33. N. Penina, L. Seguina, B. Geranda, M. Touboula, and G. Nowogrocki (2002). J. Alloys Compd. 334, 97.

    Article  Google Scholar 

  34. Y. Zhao, S. Pan, F. Li, Y. Wang, X. Fan, X. Dong, D. Jia, J. Guo, and Z. Zhou (2011). Solid State Sci. 13, 82.

    Article  Google Scholar 

  35. L. Wang, S. Pan, L. Chang, J. Hu, and H. Yu (2012). Inorg. Chem. 51, 1852.

    Article  CAS  Google Scholar 

  36. A. B. P. Lever, Inorganic Electronic Spectroscopy (Elsevier, New York, 1984).

    Google Scholar 

  37. J. S. Y. Marzouk, L. I. Soliman, M. S. Gaafar, H. A. Zayed, and A. H. Serag El-Deen (2012). Appl. Sci. Res. 8, (4), 2325.

    CAS  Google Scholar 

  38. M. A. Azooz, T. H. M. Abou Aiad, F. H. ElBatal, and G. ElTabii (2008). Indian J. Pure Appl. Phys. 46, 880.

    CAS  Google Scholar 

  39. P. Naresh, G. NagaRaju, C. H. SrinivasaRao, S. V. G. V. A. Prasad, V. RaviKumar, and N. Veeraiah (2012). Phys. B 407, 712.

    Article  CAS  Google Scholar 

  40. A. Thulasiramudu and S. Buddhudu (2006). J. Quant. Spectroscopy Radiat. Transf. 102, 212.

    Article  CAS  Google Scholar 

  41. G. Nagarjuna, T. Satyanarayana, Y. Gandhi, P. V. V. Satyanarayana, and N. Veeraiah (2010). Solid State Commun. 150, 9.

    Article  CAS  Google Scholar 

  42. G. B. Bagihalli, P. G. Avaji, S. A. Patil, and P. S. Badami (2008). Eur. J. Med. Chem. 43, 2639.

    Article  CAS  Google Scholar 

  43. B. G. Tweedy (1964). Phytopathology 55, 910.

    Google Scholar 

  44. B. N. Meyer, N. R. Ferrigni, J. E. Putnam, L. B. Jacobsen, D. E. Nichols, and J. L. McLaughlin (1982). Planta Med. 45, 31.

    Article  CAS  Google Scholar 

  45. Z. H. Chohan, C. T. Supuran, and A. Scozzafava (2004). J. Enzyme Inhib. Med. Chem. 19, (1), 79.

    Article  CAS  Google Scholar 

  46. Z. H. Chohan and M. Praveen (2001). Appl. Organomet. Chem. 15, 617.

    Article  CAS  Google Scholar 

  47. S. M. Emam, A. S. El-Tabl, H. M. Ahmed, and E. A. Emad (2014). Arab. J. Chem. doi:10.1016/j.arabjc.2014.05.019.

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, Université de Carthage, 7021, Zarzouna, Tunisia

    Nabil Jemai, Mohamed Rzaigui & Samah Akriche

Authors
  1. Nabil Jemai
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Mohamed Rzaigui
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Samah Akriche
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Samah Akriche.

Electronic Supplementary Material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOCX 4122 kb)

Supplementary material 2 (DOCX 28 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Jemai, N., Rzaigui, M. & Akriche, S. Stabilization of Hexaborate Net with Mixed Co(II) Metal and Organic Cations: Synthesis, Rationale Characterization, Comparative Study and Enhancement of the Bioactivity. J Clust Sci 26, 2051–2064 (2015). https://doi.org/10.1007/s10876-015-0905-7

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10876-015-0905-7

Keywords

Search

Navigation