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Clean and Heterogeneous Condensation of 1,2-Diamines with 1,2-Dicarbonyls Catalyzed by {Mo132} Giant Ball Nanocluster

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Abstract

Catalytic efficiency of Keplerate {Mo132} nanoball in the condensation of 1,2-diketones and 1,2-diamines in ethanol under heterogeneous conditions is exploited. Quinoxaline and bipyrazine derivatives were produced safely in high yields and isolated easily from the reaction mixture by filtration. The recovery of the nanocatalyst was easy and efficient and its structure and activity preserved after recovering.

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Scheme 1
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Scheme 2

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Acknowledgements

Support for this work by Research Council of University of Birjand is highly appreciated.

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Authors and Affiliations

  1. Catalysis Research Laboratory, Department of Chemistry, Faculty of Science, University of Birjand, 97179-414, Birjand, Iran

    Abdolreza Rezaeifard, Maasoumeh Jafarpour, Reza Haddad & Hasan Tavallaei

  2. Chemistry Department, Payame Noor University, 19395-4697, Tehran, Iran

    Mohammad Hakimi

Authors
  1. Abdolreza Rezaeifard
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  2. Maasoumeh Jafarpour
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  3. Reza Haddad
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  4. Hasan Tavallaei
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  5. Mohammad Hakimi
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Correspondence to Abdolreza Rezaeifard or Maasoumeh Jafarpour.

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Rezaeifard, A., Jafarpour, M., Haddad, R. et al. Clean and Heterogeneous Condensation of 1,2-Diamines with 1,2-Dicarbonyls Catalyzed by {Mo132} Giant Ball Nanocluster. J Clust Sci 26, 1439–1450 (2015). https://doi.org/10.1007/s10876-015-0876-8

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