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Synthesis and Characterization of First 3-D Inorganic–Organic Hybrids Based on Keggin Polyoxometalate and Melamine with Three Layers Solvent Diffusion Method

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Abstract

Two new organic–inorganic Keggin-based hybrids, namely, (MELH2)1.5(MELH)2 (AcNit)[PMo12O40]·2H2O (1) and (MELH)2(H3O)[PMo12O40]·8H2O (2), (MELH2 = C3N6H8 2+, MELH = C3N6H7 + and AcNit = CH3CN) were synthesized in room temperature and characterized by elemental analysis, Fourier transform infrared and UV spectroscopes and single crystal X-ray diffraction. The X-ray diffraction analysis show that the complex 1 constructed from Keggin polyoxoanions and melamine (MEL) cations, exhibits an extended three-dimensional (3D) supramolecular network via hydrogen bond and π–π stack interactions. Compound 2 presents an intriguing double Keggin-anion template 3D structure, made up of [PMo12O40]3− Keggin type polyoxoanions linked with MEL cations through van der Waals interactions. Crystal structure analysis reveals that these are the first Keggin polyoxoanion supported MEL cations.

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Acknowledgments

Authors thank the Department of Chemistry of Ferdowsi University of Mashhad, Mashhad, Iran, for financial support under Grant No. 3/17564. Also we thank Ms. Ashrafi for IR spectroscopy, Ms. Rajabzadeh for cyclic voltammograms, Mr Rajabzadeh for CHN analysis and Dr. Darrudi for UV spectroscopy.

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Authors and Affiliations

  1. Department of Chemistry, Ferdowsi University of Mashhad, 917751436, Mashhad, Iran

    A. Farhadipour, M. H. Alizadeh, H. Eshghi & A. R. Salimi

  2. Department of Chemistry, Shahid Beheshti University, G. C., Evin, 1983963113, Tehran, Iran

    B. Notash

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  1. A. Farhadipour
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  2. M. H. Alizadeh
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  3. H. Eshghi
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Correspondence to A. Farhadipour.

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Farhadipour, A., Alizadeh, M.H., Eshghi, H. et al. Synthesis and Characterization of First 3-D Inorganic–Organic Hybrids Based on Keggin Polyoxometalate and Melamine with Three Layers Solvent Diffusion Method. J Clust Sci 26, 1619–1631 (2015). https://doi.org/10.1007/s10876-015-0860-3

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  • DOI: https://doi.org/10.1007/s10876-015-0860-3

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