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A New 2D Network Constructed from the Extension of Transition-Metal-Grafted ε-Keggin Polyoxoanion by a Bridging Organic Carboxylate

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Abstract

By introducing a bridging ligand of 5-methylisophthalic acid (shortened as 5-mip) into the tetrahedral Zn4-ε-Keggin system, a new 2D network of [TBA]3[H4PMo V8 Mo VI4 O40Zn4][C7H6(COO)2]2 (1) was synthesized under hydrothermal condition. It was characterized by FT-IR, BET, TGA/DSC-MASS analysis, powder X-ray diffraction and single-crystal X-ray diffraction, respectively. Besides, compound 1 shows remarkable electrocatalytic activity towards bromate reduction.

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Acknowledgments

This work is financially supported by the NNSF of China (Nos. 21301152, 21371150), Foundation from the Priority Academic Program Development of Jiangsu Higher Education Institutions, Fostering Foundation of Yangzhou University (Nos. 2012CXJ012, 2012CXJ017).

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002, People’s Republic of China

    Bao-Xia Dong, Lu Chen, Shi-Yang Zhang, Yi-Chen Wu, Hui Tian, Jun Ge, Liang Song, Yun-Lei Teng & Wen-Long Liu

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  1. Bao-Xia Dong
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  2. Lu Chen
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  3. Shi-Yang Zhang
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Correspondence to Bao-Xia Dong or Yun-Lei Teng.

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Dong, BX., Chen, L., Zhang, SY. et al. A New 2D Network Constructed from the Extension of Transition-Metal-Grafted ε-Keggin Polyoxoanion by a Bridging Organic Carboxylate. J Clust Sci 26, 1595–1605 (2015). https://doi.org/10.1007/s10876-015-0858-x

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