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Protonated 2-Aminonicotinic Acid as Charge Complement in POM-Based Inorganic–Organic Hybrids: Synthesis, Crystal Structure and Characterization

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Abstract

Two supramolecular compounds, (2-HANA)4(SiW12O40)·12H2O (1) and (H3O)(2-HANA)2(HPW12O40)·11H2O (2), ANA = 2-aminonicotinic acid, were synthesized in conventional method in aqueous solution and characterized with elemental analysis, IR spectrography, thermal analysis. Their crystal structures were determined with X-ray single-crystal diffraction and CV behavior were examined. In the compounds ANA is protonated and acts as charge complement and hydrogen bond donor and acceptor. In 1 there is a supramolecular chain formed through fourfold hydrogen bonds between water molecules and SiW12 anions, and in 2 a supramolecular layer is formed by hydrogen bonds between protonated O1W molecules and PW12 anions. The protonated water molecule is identified from IR spectrum of 2.

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Authors and Affiliations

  1. Key Laboratory of Polyoxometalates Science of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun, 130024, People’s Republic of China

    Dong-Xiao Wang, Ya-Guang Chen & Shan Wei

  2. Department of Pharmaceutics, Changchun Medical College, Changchun, People’s Republic of China

    Hong-Bo Liu

Authors
  1. Dong-Xiao Wang
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  2. Hong-Bo Liu
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  3. Ya-Guang Chen
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  4. Shan Wei
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Correspondence to Ya-Guang Chen.

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Wang, DX., Liu, HB., Chen, YG. et al. Protonated 2-Aminonicotinic Acid as Charge Complement in POM-Based Inorganic–Organic Hybrids: Synthesis, Crystal Structure and Characterization. J Clust Sci 26, 1567–1576 (2015). https://doi.org/10.1007/s10876-015-0851-4

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  • DOI: https://doi.org/10.1007/s10876-015-0851-4

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