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Synthesis, Structure and Fluorescent Property of a New Isolated Co6Mg9 Heteronuclear Cluster

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Abstract

A novel zero-dimensional Co6Mg9 heteronuclear cluster based on N-(phosphonomethyl)imino-diacetic acid (H4PMIDA) and 1,3,5-benzenetricarboxylate acid (H3BTC) multifunctional ligands, [Co6Mg9(PMIDA)6(H2O)24]·(BTC)2·22H2O (1), has been synthesized under hydrothermal conditions and characterized by elemental analyses, IR spectra, thermal analyses, and single-crystal X-ray diffraction. The complex 1 exhibits a isolated cationic 15 heteronuclear cluster [Co6Mg9(PMIDA)6(H2O)24]6+, and its charges are balanced by two anionic BTC3−. Each isolated cluster is further extended into a 3D supramolecular network through very extensive O–H···O hydrogen bonds. Moreover, the solid-state fluorescent property of the complex 1 has also been investigated at room temperature.

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Authors and Affiliations

  1. Department of Chemistry and Chemical Engineering, Shaanxi Xueqian Normal University, Xi’an, 710100, People’s Republic of China

    Xiao-Lan Wang & Jun-Feng Wang

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  1. Xiao-Lan Wang
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  2. Jun-Feng Wang
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Correspondence to Jun-Feng Wang.

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Wang, XL., Wang, JF. Synthesis, Structure and Fluorescent Property of a New Isolated Co6Mg9 Heteronuclear Cluster. J Clust Sci 26, 1527–1535 (2015). https://doi.org/10.1007/s10876-015-0843-4

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  • DOI: https://doi.org/10.1007/s10876-015-0843-4

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