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Synthesis and Crystal Structure of Potassium–Nickel Heteropoly Hexatungstonickelate (II) K3Ni0,5[Ni(OH)6W6O18]·12H2O with Anderson-Type Anion and Potassium–Nickel Paratungstate B K6Ni2[W12O40(OH)2]·22H2O

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Abstract

Conditions necessary for the formation of potassium–nickel paratungstate B K6Ni2[W12O40(OH)2]·22H2O (1) and potassium–nickel heteropoly hexatungstonickelate (II) with Anderson type anion K3Ni0,5[Ni(OH)6W6O18]·12H2O (2) in Ni(NO3)2–K2WO4–HNO3–H2O solution, acidified up to Z = ν(H+)/ν(WO4 2−) = 1,00, were established. The synthesized salts 1 and 2 were examined using chemical analysis, X-ray single crystal analysis and FTIR spectroscopy. The compound 1 crystallizes in the triclinic system, space group \( \bar{P} \), Mr = 3,628.59, a = 10.617(3) Å, b = 11.818(2) Å, c = 13.454(3) Å, α = 68.034(18)°, β = 76.96(2)°, γ = 63.53(2)°, V = 1,398.0(5); the compound 2 crystallizes in the monoclinic system, space group P2 1 /n, Mr = 1,914.71, a = 11.2586(3) Å, b = 11.4933(6) Å, c = 26.1158(15) Å, α = 100.938(4)°, V = 3,318.0(3) Å3. In the structure 1 paratungstate B anion [W12O40(OH)2]10− is centrosymmetric and occupies the center [[1/2,0,1/2]], while 2D layers consist of isopolyanion and potassium polyhedra KOn (n = 8, 10), forming the 3D structure through NiO6 octahedra. The structure 2 comprises Anderson type anions [Ni(OH)6W6O18]4−, cationic polyhedra NiO6, KO8 and uncoordinated H2O molecules.

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Acknowledgments

The present study was financially supported by the Ministry of Education and Science of Ukraine, Grant ID 0113U001530.

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Authors and Affiliations

  1. Department of Inorganic Chemistry, Faculty of Chemistry, Donetsk National University, Donetsk, 83001, Ukraine

    Nadiia I. Gumerova, Kateryna V. Kasyanova, Georgiy M. Rozantsev & Sergii V. Radio

  2. State Scientific Institution “Institute for Single Crystals” of NAS of Ukraine, Kharkiv, 61001, Ukraine

    Vyacheslav N. Baumer

  3. Department of Inorganic Chemistry, Faculty of Chemistry, V. N. Karazin Kharkiv National University, Kharkiv, 61022, Ukraine

    Vyacheslav N. Baumer

Authors
  1. Nadiia I. Gumerova
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  2. Kateryna V. Kasyanova
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  3. Georgiy M. Rozantsev
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  4. Vyacheslav N. Baumer
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  5. Sergii V. Radio
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Correspondence to Nadiia I. Gumerova.

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Gumerova, N.I., Kasyanova, K.V., Rozantsev, G.M. et al. Synthesis and Crystal Structure of Potassium–Nickel Heteropoly Hexatungstonickelate (II) K3Ni0,5[Ni(OH)6W6O18]·12H2O with Anderson-Type Anion and Potassium–Nickel Paratungstate B K6Ni2[W12O40(OH)2]·22H2O. J Clust Sci 26, 1171–1186 (2015). https://doi.org/10.1007/s10876-014-0805-2

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  • DOI: https://doi.org/10.1007/s10876-014-0805-2

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