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Synthesis, Crystal Structure and Magnetic Property of Double μ 6-CO3 2− Centered Nonanuclear Ni(II) Cluster

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Abstract

A novel nonanuclear nickel cluster [Ni9(HL)6(μ 3-OH)6(μ 6-CO3)2(H2O)6]·3H2O·(OH)2(1) (H2L=3-(Pyridine-3-sulfonylamino)-propionic acid) has been synthesized and structurally determined by elemental analysis, IR, and X-ray single crystal diffraction. Complex 1 consists of a nonanuclear nickel (II) cage with double μ 6-CO3 2− bridge ant it represents the first nonanuclear nickel (II) cluster whit HL ligand. Magnetic studies indicated that the [Ni9(HL)6(μ 3-OH)6(μ 6-CO3)2(H2O)6]2+ core displays dominant antiferromagnetic interaction between nickel ions.

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Acknowledgments

This work was supported by Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources (Guangxi Normal University), Ministry of Education of China (No. CMEMR2011-13, CMEMR2011-07), the Scientific research and technological development project of Guilin (No. 20110330) and the National Nature Science Foundation of China (No. 21161006).

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Authors and Affiliations

  1. School of Chemistry and Pharmaceutical Sciences (Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, Ministry of Education of China), Guangxi Normal University, Guilin, 541004, People’s Republic of China

    Cui Cui Wang, Hai Ye Li, Xiao Qiang Zhang & Yi Min Jiang

  2. College of Chemistry and Bioengineering (Guangxi Key Laboratory of Environmental Friendly Electromagnetic Chemistry Function Materials), Guilin University of Technology, Guilin, 541004, People’s Republic of China

    Shu Hua Zhang

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  1. Cui Cui Wang
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Wang, C.C., Li, H.Y., Zhang, X.Q. et al. Synthesis, Crystal Structure and Magnetic Property of Double μ 6-CO3 2− Centered Nonanuclear Ni(II) Cluster. J Clust Sci 26, 1055–1065 (2015). https://doi.org/10.1007/s10876-014-0796-z

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