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Bis(imidazole) Cation Templates and Subtle Effect: Syntheses and Characterization of Three New Pb(II) Halide Supramolecular Polymers

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Abstract

Three novel cation-templated complexes, {(dmb)[Pb2Cl2I4]}n (1), {(ddb)[Pb2I6]}n (2), {(dmh)[Pb2I6]}n (3) (dmb = α,α-di(3-methylimidozole-1-yl)benzene dichloride, ddb = α,α-di(2,3-dimethylimidozole-1-yl)benzene dichloride, dmh = 1,6-di(3-methylimidozole) hexane have been synthesized via the self-assembly reaction in solution. The X-ray crystallography shows these compounds were all composed of imidazole organic dications and halocluster anions. It is the H-bonds and electrostatic interactions between the organic counteractions and inorganic moieties that do the contribution to the crystal packing. These compounds have been further characterized by IR spectroscopy, UV–Vis spectra and thermostability properties.

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References

  1. O. Kahn (2000). Acc. Chem. Res. 33, 647.

    Article  CAS  Google Scholar 

  2. A. J. Blake, N. R. Champness, P. Hubberstey, W.-S. Li, M. Schrorder, M. Withersby, and M. A. Schroder (1999). Coord. Chem. Rev. 183, 117.

    Article  CAS  Google Scholar 

  3. B. F. Hoskins and R. Robson (1989). J. Am. Chem. Soc. 111, 5962.

    Article  CAS  Google Scholar 

  4. V. A. Russel and M. D. Ward (1996). Chem. Mater. 8, 1654.

    Article  Google Scholar 

  5. S. Subramanian and M. Zaworotko (1994). Coord. Chem. Rev. 137, 357.

    Article  CAS  Google Scholar 

  6. C. W. Padgett, R. D. Walsh, G. W. Drake, T. W. Hanks, and W. T. Pennington (2005). Cryst. Growth Des. 5, 737.

    Article  CAS  Google Scholar 

  7. H.-H. Li, Z.-R. Chen, L.-G. Sun, Z.-X. Lian, X.-B. Chen, J.-B. Li, and J.-Q. Li (2010). Cryst. Growth Des. 10, 1068.

    Article  CAS  Google Scholar 

  8. G.-E. Wang, X.-M. Jiang, M.-J. Zhang, H.-F. Chen, B.-W. Liu, M.-S. Wang, and G.-C. Guo (2013). CrystEngComm. 15, 10399.

    Article  CAS  Google Scholar 

  9. B. R. Vincent, K. N. Robertson, T. S. Cameron, and O. Knop (1987). Can. J. Chem. 65, 1042.

    Article  CAS  Google Scholar 

  10. L. Dobrzycki and K. Woźniak (2008). CrystEngComm. 10, 577.

    Article  CAS  Google Scholar 

  11. L. Dobrzycki and K. Woźniak (2009). J. Mol. Struct. 921, 18.

    Article  CAS  Google Scholar 

  12. H. Krautscheid and F. Vielsack (1999). J. Chem. Soc., Dalton Trans. 2731.

  13. D. G. Billing and A. Lemmerer (2009). CrystEngComm. 11, 1549.

    Article  CAS  Google Scholar 

  14. A. Okrut and C. Feldmann (2006). Z. Anorg. Allg. Chem. 632, 409.

    Article  CAS  Google Scholar 

  15. J.-M. Yue, Y.-Y. Niu, B. Zhang, S. W. Ng, and H.-W. Hou (2011). CrystEngComm. 13, 2571.

    Article  CAS  Google Scholar 

  16. A. Cuna, I. Aguiar, A. Gancharov, M. Pérez, and L. Fornaro (2004). Cryst. Res. Technol. 39, 899.

    Article  CAS  Google Scholar 

  17. S. Wang, D. B. Mitzi, C. A. Feild, and A. Guloy (1995). J. Am. Chem. Soc. 117, 5297.

    Article  CAS  Google Scholar 

  18. D. G. Billing and A. Lemmerer (2006). CrystEngComm. 8, 686.

    Article  CAS  Google Scholar 

  19. G.-E. Wang, G. Xu, M.-S. Wang, J. Sun, Z.-N. Xu, and G.-C. Guo (2012). J. Mater. Chem. 22, 16742.

    Article  CAS  Google Scholar 

  20. A. Trigui, H. Abid, A. Mlayah, and Y. Abid (2012). Synth. Met. 162, 1731.

    Article  CAS  Google Scholar 

  21. J. Calabrese, N. L. Jones, R. L. Harlow, N. Herron, D. L. Thorn, and Y. Wang (1991). J. Am. Chem. Soc. 113, 2328.

    Article  CAS  Google Scholar 

  22. D. B. Mitzi (1996). Chem. Mater. 8, 791.

    Article  CAS  Google Scholar 

  23. X.-H. Zhu, N. Mercier, A. Riou, P. Blanchard and P. Frère (2002). Chem. Commun. 18, 2160.

  24. N. Mercier (2005). CrystEngComm. 7, 429.

    Article  CAS  Google Scholar 

  25. D. G. Billing and A. Lemmerer (2008). New J. Chem. 32, 1736.

    Article  CAS  Google Scholar 

  26. A. B. Corradi, A. M. Ferrari, G. C. Pellacani, A. Saccani, F. Sandrolini, and P. Sgarabotto (1999). Inorg. Chem. 38, 716.

    Article  CAS  Google Scholar 

  27. A. B. Corradi, A. M. Ferrari, L. Righi, and P. Sgarabotto (2001). Inorg. Chem. 40, 218.

    Article  CAS  Google Scholar 

  28. L. Dobrzycki and K. Woźniak (2008). CrystEngComm. 10, 525.

    Article  CAS  Google Scholar 

  29. Z.-J. Zhang, G.-C. Guo, G. Xu, M.-L. Fu, J.-P. Zhou, and J.-S. Huang (2006). Inorg. Chem. 45, 10028.

    Article  CAS  Google Scholar 

  30. Z.-J. Zhang, S.-C. Xiang, G.-C. Guo, G. Xu, M.-S. Wang, J.-P. Zhou, S.-P. Guo, and J.-S. Huang (2008). Angew. Chem. Int. Ed. 47, 4149.

    Article  CAS  Google Scholar 

  31. G.-E. Wang, M.-S. Wang, X.-M. Jiang, Z.-F. Liu, R.-G. Lin, L.-Z. Cai, G.-C. Guo, and J.-S. Huang (2011). Inorg. Chem. Commun. 14, 1957.

    Article  CAS  Google Scholar 

  32. D. G. Billing and A. Lemmerer (2007). CrystEngComm. 9, 236.

    Article  CAS  Google Scholar 

  33. Z.-M. Shan, Y.-L. Wang, H.-X. Guo, Q.-Y. Liu, N. Zhang, E.-L. Yang, and L.-Q. Li (2011). Inorg. Chim. Acta. 366, 141.

    Article  CAS  Google Scholar 

  34. M. Baron, C. Tubaro, M. Basato, M. M. Natile, and C. Graiff (2013). J. Organomet. Chem. 723, 108.

    Article  CAS  Google Scholar 

  35. H. Ibrahim, N. A. Koorbanally, D. Ramjugernath, M. D. Bala, and V. O. Nyamori (2012). Z. Anorg. Allg. Chem. 638, 2304.

    CAS  Google Scholar 

  36. Q.-B. Liu, F. V. Rantwijk, and R. A. Sheldon (2006). J. Chem. Technol. Biotechnol. 81, 401.

    Article  CAS  Google Scholar 

  37. SHELXTL Reference Manual version 5 (Siemens Energy & Automation, Madison, WI, 1994).

    Google Scholar 

  38. S.-B. Miao, Z.-H. Li, B.-M. Ji, D.-S. Deng, C.-Y. Xu, and L. Zhou (2014). J. Clust. Sci. 25, 1137.

    Article  CAS  Google Scholar 

  39. Y.-Z. Qiao, W.-Z. Fu, J.-M. Yue, Y.-Y. Niu, X.-C. Liu, and H.-W. Hou (2012). CrystEngComm. 14, 3241.

    Article  CAS  Google Scholar 

  40. H.-H. Li, Y.-Y. Xing, Z.-X. Lian, A.-W. Gong, H.-Y. Wu, Y. Li, and Z.-R. Chen (2013). CrystEngComm. 15, 1721.

    Article  CAS  Google Scholar 

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Acknowledgments

Research efforts in the Niu group are supported by the National Science Foundation of China (No. 21171148, J1103309). Foundation and Frontier Research Project of Henna Province (No. 132300410265) and Xinxiang Science and Technology Key projects Fund (ZG13012).

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Authors and Affiliations

  1. College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou, 450001, People’s Republic of China

    Chao-Hai Wang, Cheng-Jie Ma, Zhi-Peng Huang, Yu-Xia Zai, Qing Yang, Li Li, Yu Liang & Yun-Yin Niu

  2. College of Chemistry and Chemical Engineering, Xinxiang University, Xinxiang, 453000, People’s Republic of China

    Chao-Hai Wang, Cheng-Jie Ma, Zhi-Peng Huang, Yu-Xia Zai, Qing Yang, Li Li, Yu Liang & Yun-Yin Niu

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  1. Chao-Hai Wang
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  2. Cheng-Jie Ma
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  3. Zhi-Peng Huang
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  4. Yu-Xia Zai
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  5. Qing Yang
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  8. Yun-Yin Niu
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Correspondence to Yu Liang or Yun-Yin Niu.

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Wang, CH., Ma, CJ., Huang, ZP. et al. Bis(imidazole) Cation Templates and Subtle Effect: Syntheses and Characterization of Three New Pb(II) Halide Supramolecular Polymers. J Clust Sci 26, 1027–1039 (2015). https://doi.org/10.1007/s10876-014-0784-3

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  • DOI: https://doi.org/10.1007/s10876-014-0784-3

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