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Synthesis and Crystal Structure of the Coordination Polymer of Ni-Mo8-Pyrazinecarboxylic Acid

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Abstract

An inorganic–organic hybrid compound [Ni4(pzac)4(H2O)8(β-Mo8O26)]·2H2O (1), pzac = 2- pyrazinecarboxylic acid, was synthesized hydrothermally and characterized by IR spectrum, TGA, X-ray single-crystal diffraction. Photoluminescence property has been investigated. In 1 pzac coordinates to Ni1 with a chelating mode and bridges Ni2 forming a one-dimensional undulate chain structure. Ni atom accepts a terminal oxygen atom of [β-Mo8O26]4− anion with a little longer Ni–O distances of 2.685 Å and 2.767 Å. [β-Mo8O26]4− anion links four Ni atoms of four chains, forming a three-dimensional covalent framework. Lattice water molecules fill the vacancies of the framework.

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Authors and Affiliations

  1. Key Laboratory of Polyoxometalates Science of Ministry of Education, College of Chemistry, Northeast Normal University, Changchun, 130024, Jilin, China

    Xiao-Min Li, Ya-Guang Chen, Shi Zhou & Tian Shi

  2. Department of Chemistry, Yili Normal University, Yining, 835000, Xingjiang, China

    Xiao-Min Li

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  1. Xiao-Min Li
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  2. Ya-Guang Chen
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  3. Shi Zhou
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  4. Tian Shi
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Correspondence to Ya-Guang Chen.

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Li, XM., Chen, YG., Zhou, S. et al. Synthesis and Crystal Structure of the Coordination Polymer of Ni-Mo8-Pyrazinecarboxylic Acid. J Clust Sci 25, 1687–1693 (2014). https://doi.org/10.1007/s10876-014-0766-5

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  • DOI: https://doi.org/10.1007/s10876-014-0766-5

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