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Cluster Organic Framework Based on Er3 and Cu5 Cluster Units

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Abstract

A novel cluster organic framework, Er3Cu5I4L10(H2O) (1, L = 4-pyridin-3-yl-benzonate), has been hydrothermally made and structurally characterized by single crystal X-ray diffraction. Structure analysis shows [Er3(COO)6]3+ (Er3) clusters are linked by carboxylate groups generating one dimensional wave-like chain, which further extended by Cu5I4 + (Cu5) clusters into three dimensional heterometallic cluster organic framework. From the perspective of topology, such framework defines a new (7,9)-connected net, considering Er3 and Cu5 cores as the nodes. Furthermore, the elemental analysis, powder X-ray diffraction, infrared spectra and thermogravimetric analysis are also studied.

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Acknowledgments

This work was supported by the NSFC (Nos. 91122028, 21221001, and 50872133), the 973 Program (Nos. 2014CB932101 and 2011CB932504), the NSFC for Distinguished Young Scholars (No. 20725101).

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Authors and Affiliations

  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, Fujian, China

    Wei-Hui Fang & Guo-Yu Yang

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  1. Wei-Hui Fang
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Correspondence to Guo-Yu Yang.

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Fang, WH., Yang, GY. Cluster Organic Framework Based on Er3 and Cu5 Cluster Units. J Clust Sci 25, 1479–1488 (2014). https://doi.org/10.1007/s10876-014-0724-2

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