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Ligand-Participated Formation of Covalent Superlattices Containing [Cd4(μ-SPh)6] Cores with Adamantane-Like Stereochemistry

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Abstract

Hydrothermal treatment of halide mono-substituted complex of (Me4N)2[Cd4(SPh)9Cl] (1) afforded three-dimensional framework [Cd4(SPh)8]n (2), its three-dimensional framework can be destroyed by coordination with PPh3 ligand, forming a polymeric complex of [Cd4(SPh)8(PPh3)]n (3) with one-dimensional zig–zig chain structure. Complexes 1, 2 and 3 were structurally characterized by single crystal X-ray structure analysis. Their diffuse reflectance spectra and photoluminescence properties were also investigated at room temperature.

Graphical Abstract

Insert of tertiary phosphine ligands into the three-dimensional framework of [Cd4(SPh)8]n reduced its dimensionality and afforded a one-dimensional polymeric chain of [Cd4(SPh)8(PPh3)]n.

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Acknowledgments

This project was supported by the Natural Science Foundation of China (90922008). Q. F. Zhang thanks State Key Laboratory of Coordination Chemistry of Nanjing University for the assistance.

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Authors and Affiliations

  1. Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, 243002, Anhui, People’s Republic of China

    Chao Xu, Hua-Tian Shi, Zhi-Feng Xin, Ai-Quan Jia & Qian-Feng Zhang

  2. Coordination Chemistry Institute, Nanjing University, Nanjing, 210093, People’s Republic of China

    Zhi-Feng Xin & Qian-Feng Zhang

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  1. Chao Xu
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  2. Hua-Tian Shi
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  3. Zhi-Feng Xin
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Correspondence to Qian-Feng Zhang.

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Xu, C., Shi, HT., Xin, ZF. et al. Ligand-Participated Formation of Covalent Superlattices Containing [Cd4(μ-SPh)6] Cores with Adamantane-Like Stereochemistry. J Clust Sci 25, 1353–1361 (2014). https://doi.org/10.1007/s10876-014-0713-5

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