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Arsenic-Centered Molybdenum–Vanadium Polyoxometalate Supporting Three Copper Complexes

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Abstract

A novel compound [HMo VI8 V V6 AsVO42][Cu(2,2′-bpy)2]2[Cu(2,2′-bpy)]·2H2O (2,2′-bpy = 2,2′-bipyridine) 1 has been hydrothermally synthesized and structurally characterized by elemental analyses, infrared spectroscopy, ultraviolet spectroscopy, X-ray photoelectron spectroscopy, thermogravimetric analysis and single crystal X-ray diffraction. Crystal structure analysis reveals that compound 1 is a bi-capped As/Mo/V Keggin polyoxometalate tri-supported copper complexes, and exhibits an extended three-dimensional supramolecular network via hydrogen-bonding and π–π stacking interactions. The electrochemical and magnetic properties of compound 1 have been studied.

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Acknowledgments

We thank the National Natural Science Foundation of China (Grant Nos. 21071060 and 21371070), The Education Department of Jilin province science and technology research Projects during the 12th Five Year Plan (No. 2013389). Doctoral scientific research foundation of Baicheng Normal College.

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Authors and Affiliations

  1. Department of Chemistry, Baicheng Normal College, Baicheng, Jilin, 137000, People’s Republic of China

    Ying-Hua Sun, Yang Gu & Di Chen

  2. College of Chemistry and State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, Jilin University, Changchun, 130023, People’s Republic of China

    Ying-Hua Sun, Guo-Dong Li & Hai-Yang Guo

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  1. Ying-Hua Sun
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  2. Guo-Dong Li
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  3. Hai-Yang Guo
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  4. Yang Gu
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Correspondence to Ying-Hua Sun or Guo-Dong Li.

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Sun, YH., Li, GD., Guo, HY. et al. Arsenic-Centered Molybdenum–Vanadium Polyoxometalate Supporting Three Copper Complexes. J Clust Sci 25, 1341–1352 (2014). https://doi.org/10.1007/s10876-014-0712-6

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  • DOI: https://doi.org/10.1007/s10876-014-0712-6

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