Skip to main content
SpringerLink
Log in

Synthesis, Structural Characterization and Properties of Two Strontium Borates Constructed from Oxo Boron Clusters

  • Original Paper
  • Published:
Journal of Cluster Science Aims and scope Submit manuscript

Abstract

Two strontium borates Sr2[B6O9(OH)4] (1) and Sr2B5O9(OH)·H2O (2), with acentric structures have been synthesized under hydro/solvothermal conditions. Compound 1 is reported for the first time in the strontium borates system, and it crystallizes in the monoclinic space group P21 with unit cell parameters a = 6.8445(5) Å, b = 8.7033(6) Å, c = 8.4632(6) Å, β = 100.581(6)°, V = 495.58(6) Å3 and Z = 2. Its structure consists of unusual borate layers of 3, 11-membered rings, which are interconnected via Sr–O ionic bonds and hydrogen bonds to generate a 3D supramolecular network. Compound 2 is a known strontium borate, crystallizing in the monoclinic space group C 2 with a = 10.161 (13) Å, b = 7.965(4) Å, c = 6.393(11) Å, β = 128.0(2)°, V = 407.7(14) Å3 and Z = 2. Second-harmonic generation measurements on the powder samples reveal that 1 and 2 exhibits good SHG efficiency about 1.5 and 2 times that of KDP (KH2PO4) powder respectively.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. J. D. Grice, P. C. Burns, and F. C. Hawthorne (1999). Can. Mineral. 37, 731.

    CAS  Google Scholar 

  2. M. S. Wang, G. C. Guo, W. T. Chen, G. Xu, W. W. Zhou, K. J. Wu, and J. S. Huang (2007). Angew. Chem. Int. Ed. 46, 3909.

    Article  CAS  Google Scholar 

  3. S. Wang, N. Ye, W. Li, and D. Zhao (2010). J. Am. Chem. Soc. 132, 8779.

    Article  CAS  Google Scholar 

  4. H. Wu, S. Pan, K. R. Poeppelmeier, H. Li, D. Jia, Z. Chen, X. Fan, Y. Yang, J. M. Rondinelli, and H. Luo (2011). J. Am. Chem. Soc. 133, 7786.

    Article  CAS  Google Scholar 

  5. D. F. Xue, K. Betzler, and H. Hesse (2002). Appl. Phys. A. 74, 7792.

    Article  Google Scholar 

  6. M. Touboul, N. Penin, and G. Nowogrocki (2003). Solid State Sci. 5, 1327.

    Article  CAS  Google Scholar 

  7. P. S. Halasyamani (2004). Chem. Mater. 16, 3586.

    Article  CAS  Google Scholar 

  8. C. T. Chen, S. Y. Luo, X. Y. Wang, G. L. Wang, X. H. Wen, H. X. Wu, X. Zhang, and Z. Y. Xu (2009). J. Opt. Soc. Am. B. 26, 1519.

    Article  CAS  Google Scholar 

  9. Z. Y. Wu, P. Brandao, and Z. Lin (2012). Inorg. Chem. 51, 3088.

    Article  CAS  Google Scholar 

  10. H. Wu, H. Yu, Z. Yang, X. Hou, X. Su, S. Pan, K. R. Poeppelmeier, and J. M. Rondinelli (2013). J. Am. Chem. Soc. 135, 4215.

    Article  CAS  Google Scholar 

  11. P. Becker (1998). Adv. Mater. 10, 979.

    Article  CAS  Google Scholar 

  12. C. Chen, Y. Wu, A. Jiang, B. Wu, G. You, R. Li, and S. Lin (1989). J. Opt. Soc. Am. 6, 616.

    Article  CAS  Google Scholar 

  13. Y. C. Wu, T. Sasaki, A. Yokotani, H. Tang, and C. T. Chen (1993). Appl. Phys. Lett. 62, 2614.

    Article  CAS  Google Scholar 

  14. Y. Mori, I. Kuroda, S. Nakajima, T. Sasaki, and S. Nakai (1995). Appl. Phs. Lett. 67, 1818.

    Article  CAS  Google Scholar 

  15. A. Borsutzky, R. Brünger, C. Huang, and R. Wallenstein (1991). Appl. Phys. 52, 55.

    Article  Google Scholar 

  16. C. Chen, Y. Wang, B. Wu, K. Wu, W. Zeng, and L. Yu (1995). Nature 373, 322.

    Article  CAS  Google Scholar 

  17. P. Becker (1998). Adv. Mater. 10, 979.

    Article  CAS  Google Scholar 

  18. G. Zhang, Z. Liu, J. Zhang, F. Fan, Y. Liu, and P. Fu (2009). Cryst. Growth Des. 9, 3137.

    Article  CAS  Google Scholar 

  19. C. Heyward, C. McMillen, and J. Kolis (2012). Inorg. Chem. 51, 3956.

    Article  CAS  Google Scholar 

  20. C. Rong, Z. W. Yu, Q. Wang, S. T. Zheng, C. Y. Pan, F. Deng, and G. Y. Yang (2009). Inorg. Chem. 48, 3650.

    Article  CAS  Google Scholar 

  21. J. Zhou, W. H. Fang, C. Rong, and G. Y. Yang (2010). Chem. Eur. J. 16, 4852.

    Article  CAS  Google Scholar 

  22. L. Z. Wu, L. Cheng, J. N. Shen, and G. Y. Yang (2013). CrystEngComm. 15, 4483.

    Article  CAS  Google Scholar 

  23. L. Cheng, Q. Wei, H. Q. Wu, L. J. Zhou, and G. Y. Yang (2013). Chem. Eur. J. 19, 17662.

    Article  CAS  Google Scholar 

  24. L. Cheng and G. Y. Yang (2014). Chem. Commun. 50, 344.

    Article  CAS  Google Scholar 

  25. S. K. Kurtz and T. T. Perry (1968). J. Appl. Phys. 39, 3798.

    Article  CAS  Google Scholar 

  26. J. Barbier and H. Park (2001). Can. Mineral. 39, 129.

    Article  CAS  Google Scholar 

  27. G. M. Sheldrick, SHELXS97 Program for Solution of Crystal Structures (University of Göttingen, Göttingen, Germany, 1997).

  28. G. M. Sheldrick, SHELXL97 Program for Solution of Crystal Structures (University of Göttingen, Göttingen, Germany, 1997).

  29. C. L. Christ and J. R. Clark (1977). Phys. Chem. Miner. 2, 59.

    Article  CAS  Google Scholar 

  30. G. Heller (1986). Top. Curr. Chem. 131, 39.

    Article  CAS  Google Scholar 

  31. G. M. Wang, Y. Q. Sun, and G. Y. Yang (2004). J. Solid State Chem. 184, 4648.

    Article  Google Scholar 

  32. C. T. Chen, Y. C. Wu, and R. K. Li (1989). Int. Rev. Phys. Chem. 8, 65.

    Article  Google Scholar 

Download references

Acknowledgments

This work was supported by the NSFC (91122028, 21221001 and 50872133), the NSFC for Distinguished Young Scholars (20725101), the 973 program (2014CB932101 and 2011CB932504), A Project of Shandong Province Higher Educational Science and Technology Program (J13LD18) and the development project of Qingdao science and technology (13-1-4-187-jch).

Author information

Authors and Affiliations

  1. MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology, Beijing, 100081, China

    Qin Meng, Jing Xue, Bai-Feng Yang, Huan He & Guo-Yu Yang

  2. Teachers College, College of Chemistry and Environment of Qingdao University, Qingdao, 266071, Shandong, China

    Guo-Ming Wang

  3. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, 350002, Fujian, China

    Guo-Yu Yang

Authors
  1. Qin Meng
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Guo-Ming Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Jing Xue
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Bai-Feng Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Huan He
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Guo-Yu Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Guo-Ming Wang or Guo-Yu Yang.

Electronic Supplementary Material

Below is the link to the electronic supplementary material.

Supplementary material 1 (DOCX 1015 kb)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Meng, Q., Wang, GM., Xue, J. et al. Synthesis, Structural Characterization and Properties of Two Strontium Borates Constructed from Oxo Boron Clusters. J Clust Sci 25, 1319–1329 (2014). https://doi.org/10.1007/s10876-014-0710-8

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10876-014-0710-8

Keywords

Search

Navigation