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Improved Synthesis, Structure, and Solution Characterization of the Cyclic 48-Tungsto-8-Arsenate(V), [H4As8W48O184]36−

Abstract

We report on an improved synthesis and structural characterization of the cyclic 48-tungsto–8-arsenate(V) [H4As8W48O184]36− (1). The mixed lithium–potassium salt of this polyanion, K26.5Li9.5[H4As8W48O184]·90H2O (KLi-1), has been studied in the solid state by IR, single-crystal X-ray diffraction, and elemental analysis, and in solution by 183W NMR spectroscopy.

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References

  1. 1.

    M. T. Pope, Heteropoly and Isopolyoxometalates (Springer, New York, 1983).

    Book  Google Scholar 

  2. 2.

    M. T. Pope and A. Müller (1991). Angew. Chem. Int. Ed. 30, 34.

    Article  Google Scholar 

  3. 3.

    M. T. Pope and A. Müller, Polyoxometalates: From Platonic Solids to Retroviral Activity (Kluwer Academic Publishers, Dordrecht, 1994).

    Book  Google Scholar 

  4. 4.

    U. Kortz, A. Müller, J. van Slageren, J. Schnack, N. S. Dalal, and M. Dressel (2009). Coord. Chem. Rev. 253, 2315.

    CAS  Article  Google Scholar 

  5. 5.

    B. Keita, T. Liu, and L. Nadjo (2009). J. Mater. Chem. 19, 19.

    CAS  Article  Google Scholar 

  6. 6.

    U. Kortz (2009). Eur. J. Inorg. Chem. 34, 5055; Issue dedicated to Polyoxometalates.

    Google Scholar 

  7. 7.

    D.-L. Long, R. Tsunashima, and L. Cronin (2010). Angew. Chem. Int. Ed. 49, 1736.

    CAS  Article  Google Scholar 

  8. 8.

    A. Dolbecq, E. Dumas, C. R. Mayer, and P. Mialane (2010). Chem. Rev. 110, 6009.

    CAS  Article  Google Scholar 

  9. 9.

    N. V. Izarova, M. T. Pope, and U. Kortz (2012). Angew. Chem. Int. Ed. 51, 9492.

    CAS  Article  Google Scholar 

  10. 10.

    M. T. Pope and U. Kortz (2012). Encycl. Inorg. Bioinorg. Chem. doi: 10.1002/9781119951438.eibc0185.pub2.

    Google Scholar 

  11. 11.

    U. Kortz and T. Liu (2013). Eur. J. Inorg. Chem. 1011, 1556; Polyoxometalates Cluster Issue.

    Article  Google Scholar 

  12. 12.

    N. V. Izarova, N. Vankova, T. Heine, R. Ngo Biboum, B. Keita, L. Nadjo, and U. Kortz (2010). Angew. Chem. Int. Ed. 49, 1886.

    CAS  Article  Google Scholar 

  13. 13.

    J. Yan, D.-L. Long, and L. Cronin (2010). Angew. Chem. Int. Ed. 49, 4117.

    CAS  Article  Google Scholar 

  14. 14.

    M. Barsukova, N. V. Izarova, R. Ngo Biboum, B. Keita, L. Nadjo, V. Ramachandran, N. S. Dalal, N. S. Antonova, J. J. Carbó, J. M. Poblet, and U. Kortz (2010). Chem. Eur. J. 16, 9076.

    CAS  Article  Google Scholar 

  15. 15.

    J. Yan, J. Gao, D.-L. Long, H. N. Miras, and L. Cronin (2010). J. Am. Chem. Soc. 132, 11410.

    CAS  Article  Google Scholar 

  16. 16.

    J.-D. Compain, P. Mialane, A. Dolbecq, I. M. Mbomekallé, J. Marrot, F. Sécheresse, E. Riviere, G. Rogez, and W. Wernsdorfer (2009). Angew. Chem. Int. Ed. 48, 3077.

    CAS  Article  Google Scholar 

  17. 17.

    Z.-M. Zhang, Y.-G. Li, S. Yao, and E.-B. Wang (2011). Dalton Trans. 40, 6475.

    CAS  Article  Google Scholar 

  18. 18.

    X. Fang, P. Kögerler, Y. Furukawa, M. Speldrich, and M. Luban (2011). Angew. Chem. Int. Ed. 50, 5212.

    CAS  Article  Google Scholar 

  19. 19.

    L. Zhang and W. Schmitt (2011). J. Am. Chem. Soc. 133, 11240.

    CAS  Article  Google Scholar 

  20. 20.

    X. Fang and M. Luban (2011). Chem. Commun. 47, 3066.

    CAS  Article  Google Scholar 

  21. 21.

    I. M. Mbomekallé, B. Keita, L. Nadjo, R. Contant, N. Belai, and M. T. Pope (2003). Inorg. Chim. Acta, 342, 219.

    Article  Google Scholar 

  22. 22.

    I. M. Mbomekallé, B. Keita, L. Nadjo, and P. Berthet (2003). Inorg. Chem. Commun. 6, 435.

    Article  Google Scholar 

  23. 23.

    I. M. Mbomekallé, Y. W. Lu, B. Keita, and L. Nadjo (2004). Inorg. Chem. Commun. 7, 86.

    Article  Google Scholar 

  24. 24.

    L.-H. Bi, U. Kortz, M. H. Dickman, S. Nellutla, N. S. Dalal, B. Keita, L. Nadjo, M. Prinz, and M. Neumann (2006). J. Clust. Sci. 17, 143.

    CAS  Article  Google Scholar 

  25. 25.

    B. S. Bassil, S. S. Mal, M. H. Dickman, U. Kortz, H. Oelrich, and L. Walder (2008). J. Am. Chem. Soc. 130, 6696.

    CAS  Article  Google Scholar 

  26. 26.

    I. M. Mbomekallé, P. Mialane, A. Dolbecq, J. Marrot, F. Sécheresse, P. Berthet, B. Keita, and L. Nadjo (2009). Eur. J. Inorg. Chem. 34, 5194.

    Article  Google Scholar 

  27. 27.

    M. Lebrini, I. M. Mbomekallé, A. Dolbecq, J. Marrot, P. Berthet, J. Ntienoue, F. Sécheresse, J. Vigneron, and A. Etcheberry (2010). Inorg. Chem. 50, 6437.

    Article  Google Scholar 

  28. 28.

    S. S. Mal and U. Kortz (2005). Angew. Chem. Int. Ed. 44, 3777.

    CAS  Article  Google Scholar 

  29. 29.

    M. Zimmermann, N. Belai, R. J. Butcher, M. T. Pope, E. V. Chubarova, M. H. Dickman, and U. Kortz (2007). Inorg. Chem. 46, 1737.

    CAS  Article  Google Scholar 

  30. 30.

    S. S. Mal, N. H. Nsouli, M. H. Dickman, and U. Kortz (2007). Dalton Trans. 2007, 2627.

    Article  Google Scholar 

  31. 31.

    S. S. Mal, M. H. Dickman, U. Kortz, A. M. Todea, A. Merca, H. Bögge, T. Glaser, A. Müller, S. Nellutla, N. Kaur, J. van Tol, N. S. Dalal, B. Keita, and L. Nadjo (2008). Chem. Eur. J. 14, 1186.

    CAS  Article  Google Scholar 

  32. 32.

    B. S. Bassil, M. Ibrahim, S. S. Mal, A. Suchopar, R. Ngo Biboum, B. Keita, L. Nadjo, S. Nellutla, J. van Tol, N. S. Dalal, and U. Kortz (2010). Inorg. Chem. 49, 4949.

    CAS  Article  Google Scholar 

  33. 33.

    T. Boyd, S. G. Mitchell, D. Gabb, D.-L. Long, and L. Cronin (2011). Chem. Eur. J. 17, 12010.

    CAS  Article  Google Scholar 

  34. 34.

    R. Contant and A. Tézé (1985). Inorg. Chem. 24, 46104.

    Article  Google Scholar 

  35. 35.

    R. Contant and R. Thouvenot (1991). Can. J. Chem. 69 1498.

    CAS  Article  Google Scholar 

  36. 36.

    M. Ammam, I. M. Mbomekallé, B. Keita, L. Nadjo, and J. Fransaer (2010). Electrochim. Acta 55, 3118.

    CAS  Article  Google Scholar 

  37. 37.

    F. L. Sousa, H. Bögge, A. Merca, P. Gouzerh, R. Thouvenot, and A. Müller (2009). Chem. Commun. 48 7491.

    Article  Google Scholar 

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Acknowledgments

This work was supported by the Centre National de la Recherche Scientifique (UMR 8180, UMR 8000), the University of Versailles, the University of Paris-Sud, the German Science Foundation (DFG KO 2288/3-1, KO 2288/3-2), and Jacobs University. We thank Dr. Travis M. Anderson (Sandia National Laboratories, USA) for participating in the preliminary stages of this project. Figure 1 was generated by Diamond Version 3.2g (copyright Crystal Impact GbR).

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Correspondence to Israël-Martyr Mbomekallé or Ulrich Kortz.

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Louis Nadjo has deceased before publication of this work.

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Mbomekallé, IM., Bassil, B.S., Suchopar, A. et al. Improved Synthesis, Structure, and Solution Characterization of the Cyclic 48-Tungsto-8-Arsenate(V), [H4As8W48O184]36− . J Clust Sci 25, 277–285 (2014). https://doi.org/10.1007/s10876-013-0656-2

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Keywords

  • Arsenic
  • NMR
  • Polyoxometalates
  • Tungsten
  • X-ray diffraction