Skip to main content
SpringerLink
Log in

Synthesis, Crystal Structure, and Luminescent Properties of a Cadmium(II) Coordination Polymer Based on Glutaric Acid and Triazole

  • Brief Communication
  • Published:
Journal of Cluster Science Aims and scope Submit manuscript

Abstract

A new coordination polymer, [Cd7(μ 3-O)2(glut)2(Hglut)2(trz)4]n (1) (H2glut = glutaric acid and Htrz = 1,2,4-triazole), has been synthesized under hydrothermal conditions, and further characterized by elemental analysis, IR, thermogravimetric analysis and single-crystal X-ray diffraction. Complex 1 features a fairly complicated three-dimensional (3D) (3,3,6,10)-connected framework constructed from two-dimensional (2D) infinite [Cd7(μ 3-O)2(glut)4(Hglut)2]n layers and [Cd(trz)4]2− units. Moreover, the thermal stability and photoluminescent properties of 1 were also investigated.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Scheme 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

References

  1. O. R. Evans and W. Lin (2002). Acc. Chem. Res. 35, 511.

    Article  CAS  Google Scholar 

  2. E. C. Yang, H. K. Zhao, B. Ding, X. G. Wang, and X. J. Zhao (2007). Cryst. Growth Des. 7, 2009.

    Article  CAS  Google Scholar 

  3. N. W. Ockwig, O. Delgado-Friederichs, M. O’Keeffe, and O. M. Yaghi (2005). Acc. Chem. Res. 38, 176.

    Article  CAS  Google Scholar 

  4. D. Sun, D. F. Wang, X. G. Han, N. Zhang, R. B. Huang, and L. S. Zheng (2011). Chem. Commun. 47, 746.

    Article  CAS  Google Scholar 

  5. Z. Su, J. Xu, J. Fan, D. J. Liu, Q. Chu, M. S. Chen, S. S. Chen, G. X. Liu, X. F. Wang, and W. Y. Sun (2009). Cryst. Growth Des. 9, 2801.

    Article  CAS  Google Scholar 

  6. Y. F. Zeng, X. Hu, F. C. Liu, and X. H. Bu (2009). Chem. Soc. Rev. 38, 469.

    Article  CAS  Google Scholar 

  7. R. Q. Zou, H. Sakurai, S. Han, R. Q. Zhong, and Q. Xu (2007). J. Am. Chem. Soc. 129, 8402.

    Article  CAS  Google Scholar 

  8. D. T. Bradshaw, T. J. Prior, E. J. Cussen, J. B. Claridge, and M. J. Rosseinsky (2004). J. Am. Chem. Soc. 126, 6106.

    Article  CAS  Google Scholar 

  9. E. Coronado and P. Day (2004). Chem. Rev. 104, 5419.

    Article  CAS  Google Scholar 

  10. P. Macchi, A. Sironi, L. Bogani, A. Caneschi, and D. Gatteschi (2007). J. Am. Chem. Soc. 129, 9410.

    Article  Google Scholar 

  11. J. Zhao, L. Mi, J. Hu, H. Hou, and Y. Fan (2008). J. Am. Chem. Soc. 130, 15222.

    Article  CAS  Google Scholar 

  12. M. O’Keeffe (2009). Chem. Soc. Rev. 38, 1215.

    Article  Google Scholar 

  13. M. O’Keeffe, M. A. Peskov, S. J. Ramsden, and O. M. Yaghi (2008). Acc. Chem. Res. 41, 1782.

    Article  Google Scholar 

  14. N. W. Ockwig, O. Delgado-Friedrichs, M. O’Keeffe, and O. M. Yaghi (2005). Acc. Chem. Res. 38, 176.

    Article  CAS  Google Scholar 

  15. O. M. Yaghi, M. O’Keeffe, N. W. Ockwig, H. K. Chae, M. Eddaoudi, and J. Kim (2003). Nature 423, 705.

    Article  CAS  Google Scholar 

  16. D. J. Tranchemontagne, J. L. Mendoza-Cortes, M. O’Keeffe, and O. M. Yaghi (2009). Chem. Soc. Rev. 38, 1257.

    Article  CAS  Google Scholar 

  17. B. Ding, L. Yi, P. Cheng, D. Z. Liao, and S. P. Yan (2006). Inorg. Chem. 45, 5799.

    Article  CAS  Google Scholar 

  18. J. R. Li, Q. Yu, E. C. Sañudo, Y. Tao, and X. H. Bu (2007). Chem. Commun. 25, 2602.

    Article  Google Scholar 

  19. J. H. Zhou, R. M. Cheng, Y. Song, Y. Z. Li, Z. Yu, X. T. Chen, Z. L. Xue, and X. Z. You (2005). Inorg. Chem. 44, 8011.

    Article  CAS  Google Scholar 

  20. D. Sun, N. Zhang, R. B. Huang, and L. S. Zheng (2010). Cryst. Growth Des. 10, 3699.

    Article  CAS  Google Scholar 

  21. M. Chen, Z. S. Bai, Q. Liu, T.-A. Okamura, Y. Lu, and W. Y. Sun (2012). Cryst. Eng. Comm. 14, 8642.

    Article  CAS  Google Scholar 

  22. W. Ouellette, B. S. Hudson, and J. Zubieta (2007). Inorg. Chem. 46, 4887.

    Article  CAS  Google Scholar 

  23. Q. G. Zhai, C. Z. Lu, X. Y. Wu, and S. R. Battern (2007). Cryst. Growth Des. 7, 2332.

    Article  CAS  Google Scholar 

  24. H. Park, J. F. Britten, U. Mueller, J. Y. Lee, J. Li, and J. B. Parise (2007). Chem. Mater. 19, 1302.

    Article  CAS  Google Scholar 

  25. D. Olea, U. García-Couceiro, O. Castillo, J. Gómez-Herrero, and F. Zamora (2007). Inorg. Chim. Acta 360, 48.

    Article  CAS  Google Scholar 

  26. SAINT(version 6.02a) (Bruker AXS Inc., Madison, W1, 2002).

  27. G. M. Sheldrick SADABS, program for siemens area detector absorption corrections (University of Göttingen, Göttingen, 1997).

    Google Scholar 

  28. G. M. Sheldrick SHELXS97, program for crystal structure solution (University of Göttingen, Germany, 1997).

    Google Scholar 

  29. G. M. Sheldrick SHELXL97, program for crystal structure refinement (University of Göttingen, Germany, 1997).

    Google Scholar 

  30. E. C. Yang, Q. Q. Liang, X. G. Wang, and X. J. Zhao (2008). Aus. J. Chem. 61, 813.

    Article  CAS  Google Scholar 

  31. Y. Q. Chen, S. J. Liu, Y. W. Li, G. R. Li, K. H. He, Y. K. Qu, T. L. Hu, and X. H. Bu (2012). Cryst. Growth Des. 12, 5426.

    Article  CAS  Google Scholar 

  32. K. H. He, Y. W. Li, Y. Q. Chen, W. C. Song, and X. H. Bu (2012). Cryst. Growth Des. 12, 2730.

    Article  CAS  Google Scholar 

  33. X. R. Jiang, H. Y. Yuan, and Y. L. Fenge (2012). J. Solid State Chem. 191, 181.

    Article  CAS  Google Scholar 

  34. K. Nakamoto Infrared and Raman Spectra of Inorganic and Coordinated Compounds, 5th ed (Wiley & Sons, New York, 1997).

    Google Scholar 

  35. L. Wang, M. Yang, G. H. Li, Z. Shi, and S. H. Feng (2006). Inorg. Chem. 45, 2474.

    Article  CAS  Google Scholar 

  36. S. R. Li and L. Xu (2005). Inorg. Chem. 44, 3731.

    Article  Google Scholar 

  37. J. Lu, K. Zhao, Q. R. Fang, J. Q. Xu, J. H. Yu, X. Zhang, H. Y. Bie, and T. G. Wang (2005). Cryst. Growth Des. 5, 1091.

    Article  CAS  Google Scholar 

  38. K. L. Huang, Y. T. He, and M. Huang (2008). J. Coord. Chem. 61, 2735.

    Article  CAS  Google Scholar 

  39. Q. G. Zhai, C. Z. Lu, X. Y. Wu, and S. R. Battern (2007). Cryst. Growth Des. 7, 2332.

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by the National Natural Science Foundation of China (No. 21271106), the Key Project of Chinese Ministry of Education (No. 210102) and Qing Lan Project of Jiangsu Provincial Department of Education.

Author information

Authors and Affiliations

  1. School of Biochemical and Environmental Engineering, Nanjing Xiaozhuang University, Nanjing, 211171, People’s Republic of China

    Guang-Xiang Liu

Authors
  1. Guang-Xiang Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Guang-Xiang Liu.

Electronic supplementary material

Below is the link to the electronic supplementary material.

(DOCX 25 kb)

Rights and permissions

Reprints and permissions

About this article

Cite this article

Liu, GX. Synthesis, Crystal Structure, and Luminescent Properties of a Cadmium(II) Coordination Polymer Based on Glutaric Acid and Triazole. J Clust Sci 24, 935–944 (2013). https://doi.org/10.1007/s10876-013-0574-3

Download citation

  • Received:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10876-013-0574-3

Keywords

Search

Navigation