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A Novel 2D Dipyrazol-Bridged Cadmium(II) Complex Based on Tetranuclear Cd4O4 Clusters: Synthesis, Structure and Luminescence

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Abstract

A coordination polymer, {[Cd2(H2Me4bpz)(ntcaa)2(H2O)]·H2O}n (1), has been synthesized by hydrothermal reaction of cadmium sulfate octahydrate with a flexible ligand, 3, 3′, 5, 5′-tetramethyl-4, 4′-bipyrazole and an auxiliary O-donor ligands, naphthalene-4,5-dicarboxylic acid-1,8-anhydride. Naphthalene-4,5-dicarboxylic acid-1,8-anhydride comes from the in situ dehydration of the naphthalene-1,4,5,8-tetracarboxylic acid in the hydrothermal reaction. Complex 1 exhibits a 2D wave-like layer structure based on tetranuclear Cd4O4 cluster units. The 2D wave-like layers are further held together by face-to-face π–π interactions between the naphthalene rings and intermolecular hydrogen bonds to generate a 3D supra-molecular network. The luminescent property of complex 1 was investigated in the solid-state at room temperature.

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Acknowledgments

This research work was supported by National Natural Science Foundation of China (No. 21003020), Doctoral Fund of Ministry of Education of China (Grant No. 20093514120002), and Science & Technology Promotion Foundation of Fuzhou University (Grant 2009-XY-4).

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Authors and Affiliations

  1. Department of Chemistry, Fuzhou University, Fuzhou, 350108, People’s Republic of China

    Yan-Qiong Sun, Song Deng, Su-Zhi Ge, Qi Liu & Yi-Ping Chen

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  1. Yan-Qiong Sun
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Correspondence to Yan-Qiong Sun.

Electronic supplementary material

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10876_2012_527_MOESM1_ESM.doc

Crystallographic details and complete listings of the compounds have been deposited at the Cambridge Crystallographic Date Center (CCDC) as supplementary publications reference number: 857292(1) contain the supplementary crystallographic data for this paper. These data can be obtained free of charge at www.ccdc.cam.ac.uk/conts/retrieving.html.(DOC 3575 kb)

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Sun, YQ., Deng, S., Ge, SZ. et al. A Novel 2D Dipyrazol-Bridged Cadmium(II) Complex Based on Tetranuclear Cd4O4 Clusters: Synthesis, Structure and Luminescence. J Clust Sci 24, 605–617 (2013). https://doi.org/10.1007/s10876-012-0527-2

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