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Solvothermal Synthesis and Structure of a New Indium-Substituted Polyoxotungstate: [(CH3)2NH2]4[In3(H2O)3(NO3)(A-α-H3PW9O34)2]·H2O

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Abstract

A rare In-substituted polyoxotungstate [(CH3)2NH2]4[In3(H2O)3(NO3)(A-α-H3PW9O34)2]·H2O (1) was synthesized by solvothermal method and structurally characterized by single-crystal X-ray diffraction, IR, and PXRD. Crystal data for 1: Orthorhombic, Pna2 1 , a = 30.4630(3) Å, b = 17.1079(14) Å, c = 21.1629(17) Å, V = 11029.4(16) Å3, Z = 4. Compound 1 is constructed from two trilacunary Keggin [A-α-H3PW9O34]6− polyoxoanions linked together by a triangular trinuclear [In3(H2O)3(NO3)]8+ indium cluster, resulting in a novel tri-indium-substituted sandwich-type polyoxotungstate.

Graphical Abstract

A rare indium-substituted polyoxotungstate has been synthesized by solvothermal assembly of lacunary polyoxotungstate precursor with p-block metal indium, which represents the first {A-α-PW9O34}-based indium-substituted polyoxotungstate.

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Acknowledgments

The authors are thankful for the financial supports from the NSF of Fujian Province (No. 2009J05022).

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Authors and Affiliations

  1. Biological and Chemical Engineering Department of Fuqing, Branch of Fujian Normal University, Fuqing, Fujian, 350300, China

    Dan Zhao & Rui-Hong Ye

Authors
  1. Dan Zhao
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  2. Rui-Hong Ye
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Corresponding author

Correspondence to Dan Zhao.

Electronic supplementary material

Below is the link to the electronic supplementary material.

10876_2011_397_MOESM1_ESM.doc

Supporting Information: CCDC 816101 contains the supplementary crystallographic data for 1. These data can be obtained free of charge via www.ccdc.cam.ac.uk/conts/retrieving.html Supplementary material 1 (DOC 159 kb)

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Zhao, D., Ye, RH. Solvothermal Synthesis and Structure of a New Indium-Substituted Polyoxotungstate: [(CH3)2NH2]4[In3(H2O)3(NO3)(A-α-H3PW9O34)2]·H2O. J Clust Sci 22, 563–571 (2011). https://doi.org/10.1007/s10876-011-0397-z

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  • DOI: https://doi.org/10.1007/s10876-011-0397-z

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