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Journal of Cluster Science

, Volume 20, Issue 2, pp 267–280 | Cite as

The First C 3-Symmetric P-Stereogenic Diphosphinomethane Trinuclear Palladium Clusters: Synthesis and Characterization

  • Christine Salomon
  • Daniel Fortin
  • Christophe Darcel
  • Sylvain Jugé
  • Pierre D. Harvey
Original Paper

Abstract

The enantiomeric ligands (R,R)- and (S,S)-bis(o-anisylphenylphosphino)methane (R,R-14 and S,S-14, respectively) were used to prepare the C 3-point group clusters [Pd3(dppm*)3(CO)(O2CCF3)](CF3CO2) with dppm* = (R,R)-14 or (S,S)-14. The chiral structure of an enantiomeric clusters (with the chiral R,R-ligand (R,R)-14) was unambiguously demonstrated by both X-ray structure determination and by circular dichroism spectroscopy.

Keywords

Chiral Cluster Palladium P-chirogenic 

Notes

Acknowledgements

PDH thanks NSERC (Natural Sciences and Engineering Research Council of Canada) and CEMOPUS (Centre sur les Matériaux Optiques et Photoniques de l’Université de Sherbrooke) for fundings. Dr. Pierre Lavigne from the Faculté de Médecine of the Université de Sherbrooke for letting us use his circular dichroism spectrometer. SJ would like also thanks Ms. M. J. Penouilh (Centre de Spectroscopie, Dijon), for its help in NMR analysis and mass spectroscopy.

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Copyright information

© Springer Science+Business Media, LLC 2009

Authors and Affiliations

  1. 1.Département de ChimieUniversité de SherbrookeSherbrookeCanada
  2. 2.Institut de Chimie Moléculaire de l’Université de Bourgogne (ICMUB) UMR CNRS 5260Université de BourgogneDijon CedexFrance
  3. 3.Sciences Chimiques de Rennes, UMR CNRS 6226Rennes CedexFrance

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