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New trans-[Re6S8(CN)4L2]n− Rhenium Cluster Complexes: Syntheses, Crystal Structures and Properties

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Abstract

Reaction of polymeric compound Cs4[Re6S8(CN)4S2/2] with aqueous solution of KOH led to formation of trans-[Re6S8(CN)4(OH)2]4− anion which was crystallized in ordered Cs1.68K2.32[Re6S8(CN)4(OH)2] · 2H2O (1a) and disordered Cs1.83K2.17[Re6S8(CN)4(OH)2] · 2H2O (1b) modifications. The presence of two types of apical ligands, inert cyanides and labile hydroxides, opened a way to other trans-[Re6S8(CN)4L2]n− rhenium cluster complexes: trans-[Re6S8(CN)4Cl2]4−, trans-[Re6S8(CN)4(H2O)Br]3−, and trans-[Re6S8(CN)4Br2]4−, crystallized as Cs1.84K1.16(H)[Re6S8(CN)4Cl2] (2), Cs1.68K1.32[Re6S8(CN)4(H2O)Br] (3), (Me4N)3(H5O2)[Re6S8(CN)4Br2] (4), and CsK{Cu(H2O)2[Re6S8(CN)4Cl2]} · 4H2O (5) salts.

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References

  1. V. Y. Fedorov, Y. V. Mironov, N. G. Naumov, M. N. Sokolov, and V. P. Fedin (2007). Usp. Khim. 76, 571.

    Google Scholar 

  2. T. G. Gray (2003). Coord. Chem. Rev. 243, 213.

    Article  CAS  Google Scholar 

  3. J. C. P. Gabriel, K. Boubekeur, S. Uriel, and P. Batail (2001). Chem. Rev. 101, 2037.

    Article  CAS  Google Scholar 

  4. Z. P. Zheng, J. R. Long, and R. H. Holm (1997). J. Am. Chem. Soc. 119, 2163.

    Article  CAS  Google Scholar 

  5. Z. P. Zheng, T. G. Gray, and R. H. Holm (1999). Inorg. Chem. 38, 4888.

    Article  CAS  Google Scholar 

  6. Z. P. Zheng and R. H. Holm (1997). Inorg. Chem. 36, 5173.

    Article  CAS  Google Scholar 

  7. M. W. Willer, J. R. Long, C. C. McLauchlan, and R. H. Holm (1998). Inorg. Chem. 37, 328.

    Article  CAS  Google Scholar 

  8. Z. N. Chen, T. Yoshimura, M. Abe, Y. Sasaki, S. Ishizaka, H. B. Kim, and N. Kitamura (2001). Angew. Chem. Int. Ed. 40, 239.

    Article  CAS  Google Scholar 

  9. Z. N. Chen, T. Yoshimura, M. Abe, K. Tsuge, Y. Sasaki, S. Ishizaka, H. B. Kim, and N. Kitamura (2001). Chem. Eur. J. 7, 4447.

    Article  CAS  Google Scholar 

  10. T. Yoshimura, K. Umakoshi, Y. Sasaki, and A. G. Sykes (1999). Inorg. Chem. 38, 5557.

    Article  CAS  Google Scholar 

  11. T. Yoshimura, K. Umakoshi, Y. Sasaki, S. Ishizaka, H. B. Kim, and N. Kitamura (2000). Inorg. Chem. 39, 1765.

    Article  CAS  Google Scholar 

  12. H. D. Selby, B. K. Roland, and Z. P. Zheng (2003). Account. Chem. Res. 36, 933.

    Article  CAS  Google Scholar 

  13. N. G. Naumov, A. V. Virovets, Y. I. Mironov, S. B. Artemkina, and V. E. Fedorov (1999). Ukr. Khim. Zhurn. 65, 21.

    CAS  Google Scholar 

  14. Y. V. Mironov, A. V. Virovets, V. E. Fedorov, N. V. Podberezskaya, O. V. Shishkin, and Y. T. Struchkov (1995). Polyhedron 14, 3171.

    Article  CAS  Google Scholar 

  15. N. G. Naumov, A. V. Virovets, N. V. Podberezskaya, and V. E. Fedorov (1997). J. Struct. Chem. (Engl. Trans.) 38, 857.

    CAS  Google Scholar 

  16. S. S. Yarovoi, Y. V. Mironov, D. Y. Naumov, Y. V. Gatilov, S. G. Kozova, S. J. Kim, and V. E. Fedorov (2005). Eur.J. Inorg. Chem. 3945.

  17. K. A. Brylev, Y. V. Mironov, S. S. Yarovoi, N. G. Naumov, V. E. Fedorov, S. J. Kim, N. Kitamura, Y. Kuwahara, K. Yamada, S. Ishizaka, and Y. Sasaki (2007). Inorg. Chem. 46, 7414.

    Article  CAS  Google Scholar 

  18. Y. V. Mironov, N. G. Naumov, K. A. Brylev, O. A. Efremova, V. E. Fedorov, and K. Hegetschweiler (2004). Angew. Chem. Int. Ed. 43, 1297.

    Article  CAS  Google Scholar 

  19. N. G. Naumov, D. V. Soldatov, J. A. Ripmeester, S. B. Artemkina, and V. E. Fedorov (2001). Chem. Commun. 571.

  20. N. G. Naumov, A. V. Virovets, M. N. Sokolov, S. B. Artemkina, and V. E. Fedorov (1998). Angew. Chem. Int. Ed. 37, 1943.

    Article  CAS  Google Scholar 

  21. N. G. Naumov, S. J. Kim, A. V. Virovets, Y. V. Mironov, and V. E. Fedorov (2006). Bull. Kor. Chem. Soc. 27, 635.

    Article  CAS  Google Scholar 

  22. BrukerAXS Inc SADABS (Version 2.11) (Bruker Advanced X-ray Solutions, Madison, Wisconsin, USA, 2004).

    Google Scholar 

  23. G. M. Sheldrick, SHELXS-97 (Program for Crystal Structure Solution, Gottingen).

  24. G. M. Sheldrick, SHELXL-97 (Program for Crystal Structure Refinement, Gottingen).

  25. J. R. Long, L. S. McCarty, and R. H. Holm (1996). J. Am. Chem. Soc. 118, 4603.

    Article  CAS  Google Scholar 

  26. V. P. Fedin, A. A. Virovets, and A. G. Sykes (1998). Inorg. Chim. Acta 271, 228.

    Article  CAS  Google Scholar 

  27. N. G. Naumov, S. B. Artemkina, A. V. Virovets, and V. E. Fedorov (1999). Solid State Sci. 1, 473.

    Article  CAS  Google Scholar 

  28. N. G. Naumov, S. B. Artemkina, A. V. Virovets, and V. E. Fedorov (2000). J. Solid State Chem. 153, 195.

    Article  CAS  Google Scholar 

  29. K. A. Brylev, G. Pilet, N. G. Naumov, A. Perrin, and V. E. Fedorov (2005). Eur.J. Inorg. Chem. 461.

  30. L. G. Beauvais, M. P. Shores, and J. R. Long (1998). Chem. Mater. 10, 3783.

    Article  CAS  Google Scholar 

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Acknowledgements

This research was supported by Seoul Research and Business Development Program (10816) and Joint Russian Taiwan grants RFBR 06-03-89503-HHC and 95WFD0300050 (Contract No RP06N02-2). N.G.N. is gratefully acknowledged Russian Science Support Foundation for financial support.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev Prosp., 630090, Novosibirsk, Russia

    Nikolay G. Naumov, Alexandra Y. Ledneva & Vladimir E. Fedorov

  2. Ewha Womans University, 11-1 Daehyun-dong, Seodaemun-gu, Seoul, 120-750, Republic of Korea

    Nikolay G. Naumov & Sung-Jin Kim

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  1. Nikolay G. Naumov
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  2. Alexandra Y. Ledneva
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  3. Sung-Jin Kim
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  4. Vladimir E. Fedorov
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Correspondence to Nikolay G. Naumov or Sung-Jin Kim.

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Naumov, N.G., Ledneva, A.Y., Kim, SJ. et al. New trans-[Re6S8(CN)4L2]n− Rhenium Cluster Complexes: Syntheses, Crystal Structures and Properties. J Clust Sci 20, 225–239 (2009). https://doi.org/10.1007/s10876-009-0233-x

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  • DOI: https://doi.org/10.1007/s10876-009-0233-x

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