Abstract
The title compound {Cu[S2P(OC2H5)2](bpe)} n (1) is constructed from flexible ligand bpe (bpe = 1,2-bis(4-pyridyl)ethane) and the Cu[S2P(OC2H5)2], which was characterized by single crystal structure determination, elemental analysis, XRD, and IR spectra. X-ray diffraction studies revealed that polymeric compound 1 consists of dinuclear module to form 1-D chains with the intramolecular Cu···Cu interactions (ca. 2.63 Å). This interaction may show a profound influence on the observed blue luminescence emission spectrum for 1. Crystal data for 1 at 293(2) K: Space group P − 1, a = 9.277(3), b = 10.504 (4), c = 31.801(1) Å, α = 92.849(3), β = 90.401(2), γ = 114.547(7)°, V = 2813.9(2) Å3, Z = 2, R 1 = 0.041.
Similar content being viewed by others
References
F. A. Cotton, G. Wilkinson, C. A. Murillo, and M. Bochmann, Advanced Inorganic Chemistry, 6th ed (Wiley, New York, 1999).
J. E. Huheey, E. A. Keiter, and R. L. Keiter, Inorganic Chemistry, 4th ed (Harper Collins College Publishers, New York, 1993).
T. Li, Z.-H. Li, and S.-W. Du (2008). J. Coord. Chem. 61, 1599.
H. H. Patterson, S. M. Kanan, and M. A. Omary (2000). Coord. Chem. Rev. 208, 227.
T. Li and S.-W. Du (2008). J. Clust. Sci. 19, 323.
Y. B. Xie and X. H. Bu (2003). J. Clust. Sci. 14, 471.
H. E. Abdou, A. A. Mohamed, and J. P. Fackler (2007). J. Clust. Sci. 18, 630.
S.-L. Zheng, M. Marc, and P. Coppens (2005). Angew. Chem. Int. Ed. 44, 4614.
J. Beck and J. Strähle (1985). Angew. Chem. Int. Ed. Engl. 24, 409.
W.-Fu. Fu, X. Gan, C.-M. Che, Q.-Y. Cao, Z.-Y. Zhou, and N.-Y. Zhu (2004). Chem. Eur. J. 10, 2228.
P. C. Ford, E. Cariati, and J. Bourassa (1999). Chem. Rev. 99, 3625.
E. Cariati, J. Bourassa, and P. C. Ford (1998). Chem. Commun. 1623.
V. W. W. Yam, W. K. Lee, and T. F. Lai (1993). Chem.Commun. 1571.
I. Gance and K. Fisher (1994). Prog. Inorg. Chem. 41, 637.
G. Henkel and B. Krebs (2004). Chem. Rev. 104, 801.
X.-Y. Tang, H.-X. Li, J.-X. Chen, Z.-G. Ren, and J.-P. Lang (2008). Coord. Chem. Rev. 252, 2026.
T. Li, Z.-H. Li, S.-M. Hu, and S.-W. Du (2006). J. Coord. Chem. 59, 945.
S.-L. Chian, L. Sikai, and R. T. T. Edward (2004). Cryst. Eng. Comm. 6, 221.
M. G. B. Drew, G. A Forsyth, M. Hasan, R. J. Hobson, and D. A. Rice (1987). J. Chem. Soc. Dalton. 1087.
G. M. Sheldrick, A program for the Siemens Area Detector Absorption Correction (University of Göttingen, 1997).
G. M. Sheldrick, SHELXS97 Program for Solution of Crystal Structures (University of Göttingen, Germany, 1997).
G. M. Sheldrick, SHELXL97 Program for Refinement of Crystal Structures (University of Göttingen, Germany, 1997).
Q.-H. Chen, S.-F. Lu, and X.-Y. Huang (1994). Chinese. J. Struct. Chem. 13, 102.
P. K. Mehrotra and R. Hoffmann (1978). Inorg. Chem. 17, 2187.
K. M. Merz and R. Hoffmann (1988). Inorg. Chem. 27, 2120.
F. H. Allen, J. A. K. Howard, V. J. Hoy, G. R. Desiraju, D. S. Reedy, and C. C. Wilson (1996). J. Am. Chem. Soc. 118, 4081.
P. D. Harvey and D. Fortin (1998). Coord. Chem. Rev. 171, 351.
C. Seward, J. Chan, D. Song, and S. Wang (2003). Inorg. Chem. 42, 1112.
Acknowledgements
The work was supported by the grants from the National Science Foundation of China (30771682) and the 07B08 Program of Fujian Agriculture and Forestry University.
Author information
Authors and Affiliations
Corresponding authors
Rights and permissions
About this article
Cite this article
Li, T., He, HB., Huang, MJ. et al. Blue Photoluminescent Dimeric Cu(I) Dithiophosphates Bridged by a Flexible Ligand 1,2-Bis(4-Pyridyl)Ethane. J Clust Sci 19, 651–658 (2008). https://doi.org/10.1007/s10876-008-0222-5
Received:
Revised:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10876-008-0222-5