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Two Coordination Modes of Bidentate Aminopyrazine Ligands in Cubane-type Cluster Complex Re4Te4Cl8(C4N3H4)4 · 2DMF

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Abstract

A new cubane-type cluster complex Re4Te4Cl4(C4H4N3)4 · 2DMF has been synthesized by reaction of Re4Te4Cl8(TeCl2)4 with 2-aminopyrazine C4H5N3 in DMF. The crystal structure of compound has been solved by X-ray single crystal diffraction method. Crystal data for Re4Te4Cl4(C4N3H4)4 · 2DMF: a = 22.8718(16) Å, b = 8.5936(7) Å, c = 20.5720(17) Å, β o = 106.493(2), V = 3877.1(5) Å3, R 1 = 0.0466, R w(F 2) = 0.1191. In the complex bidentate aminopyrazine ligands are coordinated in two different types, namely, two of four aminopyrazine ligands bind to a single rhenium atom, and each of two other ligands is coordinated as bridge between two rhenium atoms.

Graphical Abstract

A new cubane-type cluster complex Re4Te4Cl4(C4H4N3)4  · 2DMF with two coordination modes of bidentate aminopyrazine ligands has been synthesized and structurally characterized.

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References

  1. J. M. Berg and R. H. Holm, in T. G. Spiro (ed.), Iron-Sulfur Proteins Chapter 1 (Wiley-Interscience, New York, 1982).

  2. C. Perrin, R. Chevrel, and M. Sergent (1976). J. Solid State Chem. 19, 305.

    Article  CAS  Google Scholar 

  3. S. Harris (1989). Polyhedron. 8, 2843.

    Article  CAS  Google Scholar 

  4. T. Shibahara (1993). Coord. Chem. Rev. 123, 73.

    Article  CAS  Google Scholar 

  5. Y. V. Mironov and V. E. Fedorov (2002). Russ. Chem. Bull. Int. Ed. 51, 569.

    Article  CAS  Google Scholar 

  6. I. V. Kalinina and V. P. Fedin (2003). Russ. J. Coord. Chem. 29, 597.

    Article  CAS  Google Scholar 

  7. Q. Liu, L. Huang, Y. Yang, and J. Lu (1987). Jiegou Huaxue. 6, 135.

    CAS  Google Scholar 

  8. L. Huang, Y. Yang, Q. Liu, and J. Lu (1986). Jiegou Huaxue. 5, 61.

    CAS  Google Scholar 

  9. T. C. W. Mak, K. S. Jasim, and C. Chieh (1984). Angew. Chem. Int. Ed. Engl. 23, 391.

    Article  Google Scholar 

  10. T. C. W. Mak, K. S. Jasim, and C. Chieh (1985). Inorg. Chem. 24, 1587.

    Article  CAS  Google Scholar 

  11. O. A. Efremova, Y. V. Mironov, and V. E. Fedorov (2006). Eur. J. Inorg. Chem. 2533.

  12. Y. V. Mironov, T. E. Albrecht-Schmitt, and J. A. Ibers (1997). Inorg. Chem. 36, 944.

    Article  CAS  Google Scholar 

  13. APEX2, Version 1.08; SAINT, Version 7.03; Bruker Advanced X-ray Solutions (Bruker AXS Inc., Madison, WI, 2004).

  14. SADABS, Version 2.11; Bruker Advanced X-ray Solutions (Bruker AXS Inc., Madison, WI, 2004).

  15. SHELXTL, Version 6.12; Bruker Advanced X-ray Solutions (Bruker AXS Inc., Madison, WI, 2004).

  16. Y. V. Mironov, T. E. Albrecht-Schmitt, D. M. Smith, and J. A. Ibers (2001). Z. Kristallogr.–New Cryst. Struct. 216, 517.

    CAS  Google Scholar 

Download references

Acknowledgments

The research was supported by the International Bureau of the Federal Ministry of Education and Research (Grant RUS 01/241, RUS 07/005) and by PECO-NEI (RFR Contract n° 370 from the French “Ministère de l’Education Nationale, Enseignement Supérieur et Recherche”), and ECO-NET (contract n°18845ZH from the French “Ministère des Affaires Etrangères”).

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, 3, Acad. Lavrentiev prospect, Novosibirsk, 630090, Russia

    Olga A. Efremova, Yuri V. Mironov & Vladimir E. Fedorov

  2. Institut für Radiopharmazie, Forschungszentrum Dresden-Rossendorf, PF 510119, Dresden, 01314, Germany

    Hans-Jürgen Pietzsch & Holger Stephan

  3. Université de Rennes 1, CNRS UMR 6226 Sciences Chimiques de Rennes, Avenue du Général Leclerc, 35042, Rennes, France

    Christiane Perrin

Authors
  1. Olga A. Efremova
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  2. Yuri V. Mironov
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  3. Hans-Jürgen Pietzsch
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  4. Holger Stephan
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  5. Christiane Perrin
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  6. Vladimir E. Fedorov
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Correspondence to Yuri V. Mironov.

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Efremova, O.A., Mironov, Y.V., Pietzsch, HJ. et al. Two Coordination Modes of Bidentate Aminopyrazine Ligands in Cubane-type Cluster Complex Re4Te4Cl8(C4N3H4)4 · 2DMF. J Clust Sci 20, 77–81 (2009). https://doi.org/10.1007/s10876-008-0219-0

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  • DOI: https://doi.org/10.1007/s10876-008-0219-0

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