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Novel Three-Dimensional Coordination Polymers Based on [Mo6Se8(CN)6]7− Anions and Mn2+ Cations

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Abstract

Three novel coordination polymers K5[MnMo6Se8(CN)6] · 8H2O (1), (Me4N)4[{Mn(H2O)2}1.5Mo6Se8(CN)6] · 4H2O (2), and K3[{Mn2(H2O)4}Mo6Se8(CN)6] · 7H2O (3) have been synthesized by layering of a methanol solution of [Mn(salen)]CH3COO (salen–N,N′-bis(salicylidene)ethylenediamine) on an aqueous solution of K7[Mo6Se8(CN)6] · 8H2O. The compounds have been characterized by single-crystal X-ray diffraction analysis. All structures are based on negatively charged porous polymer frameworks where CN groups of [Mo6Se8(CN)6]7− cluster complexes are coordinated to Mn2+ cations. Cavities in the frameworks are filled by additional cations and solvate water molecules.

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Acknowledgements

This research was supported by the SRC program of the Korea Science and Engineering Foundation (KOSEF) (Grant : R11-2005-008-03001-0). N. G. Naumov gratefully thanks KOSEF Brain Pool for financial support. Also we thank Prof. Vladislav A. Blatov (Samara State University) for the opportunity to use TOPOS4.0 Professional software package.

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Authors and Affiliations

  1. Nikolaev Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, 3 Acad. Lavrentiev Prosp., 630090, Novosibirsk, Russia

    Konstantin A. Brylev, Nikolay G. Naumov, Alexander V. Virovets & Vladimir E. Fedorov

  2. Ewha Womans University, 11-1 Daehyun-dong, Seodaemun-gu, Seoul, 120-750, Republic of Korea

    Sung-Jin Kim

Authors
  1. Konstantin A. Brylev
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  2. Nikolay G. Naumov
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  3. Alexander V. Virovets
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  4. Sung-Jin Kim
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  5. Vladimir E. Fedorov
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Correspondence to Konstantin A. Brylev or Sung-Jin Kim.

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Brylev, K.A., Naumov, N.G., Virovets, A.V. et al. Novel Three-Dimensional Coordination Polymers Based on [Mo6Se8(CN)6]7− Anions and Mn2+ Cations. J Clust Sci 20, 165–176 (2009). https://doi.org/10.1007/s10876-008-0215-4

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