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Synthesis and Characterization of N3P3(O2C12H8)2(OC6H4Si(CH3)3)(OC6H4Br) and Its Conversion to Nanostructured Si Material

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Abstract

A new silicated cyclotriphosphazene N3P3(O2C12H8)2(OC6H4Si(CH3)3)(OC6H4Br) 1 has been synthesized and characterized. The solid state pyrolysis of 1 in air gives a nanostructured SiP2O7 3D network. The morphology of the network strongly depends on the temperature of the pyrolysis. Spinal-like columns and ring-shaped SiP2O7 are formed at 800 °C, while, at 600 °C, fused grains of about 300 nm were observed. Based on air TG and DSC thermal studies, we propose the mechanism of formation for the nanostructured network.

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Acknowledgement

This work was financially suppported by Fondecyt (Project 3060092) and MECESUP Project UCH0116.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Universidad de Chile, Casilla 653, Santiago, Chile

    Carlos Díaz & Svetlana Ushak

  2. Departamento de Química Orgánica e Inorgánica. Facultad de Química, Universidad de Oviedo, C/Julián Clavería S/N, Oviedo, 33071, Spain

    Maria Luisa Valenzuela

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  1. Carlos Díaz
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  2. Maria Luisa Valenzuela
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  3. Svetlana Ushak
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Correspondence to Carlos Díaz.

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Díaz, C., Valenzuela, M.L. & Ushak, S. Synthesis and Characterization of N3P3(O2C12H8)2(OC6H4Si(CH3)3)(OC6H4Br) and Its Conversion to Nanostructured Si Material. J Clust Sci 19, 471–479 (2008). https://doi.org/10.1007/s10876-008-0189-2

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  • DOI: https://doi.org/10.1007/s10876-008-0189-2

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