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Synthesis and Characterization of Two Extended High-dimensional Architectures Formed by Transition Metal–Glycine Complexes

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Abstract

Under the same experimental condition, changing the kinds of the transition metal (TM) of the reaction, we gained two new compounds: Na3[Cu(Gly)2][Cr(OH)6Mo6O18]·13H2O 1, and NaCo2(gly)6ClO4 2. Compound 1 exhibits an unusual three-dimensional (3D) network constructed from [Cr(OH)6Mo6O18]3− building blocks, trinuclear Na+ ions and [Cu(gly)2] coordination complexes as linkers, representing the first example of a 3D extended framework based on Anderson type polyanions and amino acid molecules. Compound 2 consists of an unusual 3D network grafted with Na[Co(gly)3]6 complexes. Moreover, compound 2 contains left-handed and right-handed helical chains.

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References

  1. C. Sanchez and F. Ribot (1994), New J. Chem. 18, 1007

    CAS  Google Scholar 

  2. P. Judeinstein and C. Sanchez (1996), J. Mater. Chem. 6, 511

    Article  CAS  Google Scholar 

  3. S. H. Feng and R. R. Xu (2001), Acc. Chem. Res. J. 34, 239

    Article  CAS  Google Scholar 

  4. X. M. Zhang, M. L. Tong and X. M. Chen (2002), Angew. Chem. Int. Ed. 41, 1029

    Article  CAS  Google Scholar 

  5. (a) B. B. Xu, Z. H. Peng, Y. G. Wei and D. R. Powell (2003), Chem. Commun. 2562; (b) M. I. Khan, E. Yohannes and D. Powell (1999), Chem. Commun. 23; (c) H. Y. An, Y. G. Li, E. B. Wang, D. R. Xiao, C. Y. Sun and L. Xu (2005), Inorg. Chem. 44, 6062

  6. (a) F. Bonhomme, J. P. Larentzos, T. M. Alam, E. J. Maginn and M. Nyman (2005), Inorg. Chem. 44, 1774; (b) H. Y. An, D. R. Xiao, E. B. Wang, Y. G. Li and L. Xu (2005), New J. Chem. 29, 667; (c) H. Y. An, E. B. Wang, D. R. Xiao, Y. G. Li and L. Xu (2005), Inorg. Chem. Commun. 8, 267

  7. (a) S. Bareyt, S. Piligkos, B. Hasenknopf, P. Gouzerh, E. Laco^ te, S. Thorimbert and M. J. Malacria, (2005), J. Am. Chem. Soc. 127, 6788; (b) H. Y. An, Y. Q. Guo, Y. G. Li, E. B. Wang, J. Lu¨, L. Xu and C. W. Hu (2004), Inorg. Chem. Commun. 7, 521

  8. (a) J. Tao, Y. Zhang, M. L. Tong, X. M. Chen, T. Yuen, C. L. Lin, X. Y. Huang and J. Li (2002), Chem. Commun. 1342; (b) B. Z. Lin and S. X. Liu (2002), Chem. Commun. 2126

  9. (a) R. O. Duthaler (2003), Angew. Chem. 115, 1005; (2003), Angew. Chem. Int. Ed. 42, 975; (b) S. M. Hu, W. X. Du, J. C. Dai, L. M. Wu, C. P. Cui, Z. Y. Fu and X. T. Wu (2001), J. Chem. Soc. Dalton Trans. 2963

  10. (a) H. Q. Ai, Y. X. Bu, P. Li, C. Zhang (2005), New J. Chem., 29, 1540; (b) T. Shoeib, C. F. Rodriquez, K. W. Michael Siu and A. C. Hopkinson (2001), Phys. Chem. Chem. Phys. 3, 853; (c) A. A. H. Abu-Nawwas, J. Cano, P. Christian, T. Mallah, G. Rajaraman, S. J. Teat, R. E. P. Winpenny and Y. Yukawa (2004), Chem. Commun. 314; (d) J. Torres, C. Kremer, E. Kremer, H.Pardo, L. Suescun, A. Mombrffl, S. DomSnguez, A. Mederos, R. Herbst-Irmer and J. M. Arrieta (2002), J. Chem. Soc. Dalton Trans. 4035

  11. (a) J. J. Zhang, T. L. Sheng, S. Q. Xia, G. Leibeling, F. Meyer, S. M. Hu, R. B. Fu, S. C. Xiang and X. T. Wu, (2004), Inorg. Chem. 43, 5472; (b) B. Q. Ma, D. S. Zhang, S. Gao, T. Z. Jin, C. H. Yan and G. X. Xu, (2000), Angew. Chem., Int. Ed. 39, 3644

    Google Scholar 

  12. L. Lisnard, A. Dolbecq, P. Mialane, J. Marrot and F. Secheresse (2004), Inorg. Chim. Acta. 357, 845

    Article  CAS  Google Scholar 

  13. A. Perloff (1970), Inorg. Chem. 9, 2228

    Article  CAS  Google Scholar 

  14. G. M. Sheldrick, SHELXL-97, Program for the Refinement of Crystal Structure. (University of Göttingen, Göttingen, Germany, 1997)

    Google Scholar 

  15. I.D. Brown and D. Altermatt (1985), Acta Cryst. B41, 244

    CAS  Google Scholar 

  16. H. Y. An, D. R. Xiao, E. B. Wang, C. Y. Sun and L. Xu, (2005), J. Mol. Struct. 743, 117

    Article  CAS  Google Scholar 

  17. J. Liu, Y. G. Li, E. B. Wang, D. R. Xiao, L. L. Fan, Z. M. Zhang and Y. Wang (2007), J. Mol. Struct. 837, 237

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was financially supported by the National Science Foundation of China (No. 20371011), Science and Technology Development Project Foundation of Jilin Province (No. 20060420), Testing Foundation of Northeast Normal University (No. 201586000/201372000), and PhD station Foundation of Ministry of Education (No. 20060200002).

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Authors and Affiliations

  1. Key Laboratory of Polyoxometalate Science of Ministry of Education, Institute of Polyoxometalate Chemistry, Department of Chemistry, Northeast Normal University, Changchun, Jilin, 130024, P.R. China

    Yu Wang, Dongrong Xiao, Yanfei Qi, Enbo Wang & Jia Liu

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  1. Yu Wang
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  2. Dongrong Xiao
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  3. Yanfei Qi
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  4. Enbo Wang
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Correspondence to Enbo Wang.

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Wang, Y., Xiao, D., Qi, Y. et al. Synthesis and Characterization of Two Extended High-dimensional Architectures Formed by Transition Metal–Glycine Complexes. J Clust Sci 19, 367–378 (2008). https://doi.org/10.1007/s10876-007-0169-y

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  • DOI: https://doi.org/10.1007/s10876-007-0169-y

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