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Journal of Cluster Science

, Volume 18, Issue 3, pp 671–683 | Cite as

Deoxygenation of Nitrosobenzene by the Electrogenerated Pd3(dppm)33-CO) Cluster

  • Cyril Cugnet
  • David Brevet
  • Sophie Dal Molin
  • Dominique Lucas
  • Yves Mugnier
  • Pierre D. Harvey
Original Paper

Abstract

The 2-electron reduction of the unsaturated Pd3(dppm)3(CO)2+ cluster ([Pd3]2+) affords the highly reactive neutral cluster [Pd3]0, which reacts with nitrosobenzene (PhNO) yielding the organic azoxybenzene product (PhN(O)NPh) via the formation of “triplet” nitrene “PhN”. The formation of [Pd33-O)] as a possible (relatively unstable) intermediate is also postulated based on MALDI-TOF findings, but not formally demonstrated. Concurrently, no reaction between [Pd3]0 and OPPh3 occurs.

Keywords

Cyclic Voltammogram Saturated Calomel Electrode Carbazole Phosphine Oxide Rotate Disk Electrode 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Notes

Acknowledgment

The Natural Sciences and Engineering Research Council of Canada (NSERC) and the Centre National de Recherche Scientifique (CNRS; UMR 5260) are acknowledged for funding.

Supplementary material

10876_2007_135_MOESM1_ESM.pdf (168 kb)
(PDF 168 kb)

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Copyright information

© Springer Science+Business Media, LLC 2007

Authors and Affiliations

  • Cyril Cugnet
    • 1
  • David Brevet
    • 1
  • Sophie Dal Molin
    • 1
  • Dominique Lucas
    • 1
  • Yves Mugnier
    • 1
  • Pierre D. Harvey
    • 2
  1. 1.Institut de Chimie Moléculaire de l’Université de Bourgogne, (ICMUB) UMR CNRS 5260Université de Bourgogne, Faculté des Sciences MirandeDijonFrance
  2. 2.Département de ChimieUniversité de SherbrookeSherbrookeCanada

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