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Hydrothermal Synthesis and Characterization of a New Arsenic–Vanadium Compound with a β-[As8V14O42(SO4)]6− anion

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Abstract

A new arsenic vanadium compound (NH4)2[N(CH3)4]4[β-As8V14O42(SO4)] 1 has been synthesized under hydrothermal conditions and characterized by single crystal X-ray diffraction, IR spectrum, elemental analysis and thermogravimetic (TG) analysis. Compound 1 crystallizes in monoclinic system with space group P2(1)/c, a = 11.4631(5) Å, b = 11.3539(5) Å, c = 24.6265(10) Å, β = 93.6620(10)°, V = 3198.6(2) Å3, Z = 2, R1 = 0.0421 and wR2 = 0.1044. The molecule structural analysis reveals that compound 1 has a β-[As8V14O42(SO4)]6− arsenic–vanadium cluster anion.

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Acknowledgments

The authors thank the Education Office Foundation of Liaoning province (05L220) for financial support.

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Authors and Affiliations

  1. Institute of Chemistry for Functionalized Materials, College of Chemistry and Chemical Engineering, Liaoning Normal University, No.850, Huanghe Road, Dalian, 116029, P. R. China

    Guangpeng Zhou, Yan Xu, Chunyan Guo & Yuguo Liu

  2. Liaoning Key Laboratory of Bio-Organic Chemistry, Dalian University, Dalian, 116622, P. R. China

    Xuefang Zheng

Authors
  1. Guangpeng Zhou
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  2. Yan Xu
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  3. Chunyan Guo
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  4. Yuguo Liu
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  5. Xuefang Zheng
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Correspondence to Yan Xu.

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Zhou, G., Xu, Y., Guo, C. et al. Hydrothermal Synthesis and Characterization of a New Arsenic–Vanadium Compound with a β-[As8V14O42(SO4)]6− anion. J Clust Sci 18, 388–395 (2007). https://doi.org/10.1007/s10876-007-0117-x

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  • DOI: https://doi.org/10.1007/s10876-007-0117-x

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