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Hydrothermal Synthesis and Crystal Structure of a Novel 3-D Porous Lanthanum Sulfate

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A new lanthanum compound with three-dimensional channels, La2(H2O)(SO4)3 has been synthesized hydrothermally by using 1,2-dizminiopnopane as a structure-directing agent (SDA). The colorless block crystals were characterized by IR, TGA, ICP and XRD. The structure was determined by single-crystal diffraction. The title compound crystallizes in the orthorhombic, P212121(No. 19) with cell parameters, a = 17.095(3) Å, b = 17.331(3) Å, c = 6.8633(12) Å, V = 1659.0(8) Å3, Z = 4, R = 0.0545, wR = 0.1246. The open framework of title compound is built up by LaO10, LaO9 polyhedra and SO4 tetrahedra, connected to form interesting eight-membered ring channels along crystallographic a axis.

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Acknowledgments

The authors thank the Education Office Foundation of Liaoning province (05L220) and Natural Foundation (20062139) for financial support.

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Authors and Affiliations

  1. The Functional and Materials Chemistry Institute, College of Chemistry and Chemical Engineering, Liaoning Normal University, Dalian, 116029, People’s Republic of China

    Shaohua Ding, Yan Xu, Linbo Nie & Wenjun Feng

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  1. Shaohua Ding
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  2. Yan Xu
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  3. Linbo Nie
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  4. Wenjun Feng
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Correspondence to Yan Xu.

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Ding, S., Xu, Y., Nie, L. et al. Hydrothermal Synthesis and Crystal Structure of a Novel 3-D Porous Lanthanum Sulfate. J Clust Sci 17, 627–636 (2006). https://doi.org/10.1007/s10876-006-0078-5

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  • DOI: https://doi.org/10.1007/s10876-006-0078-5

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