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Synthesis and Crystal Structures of Four Novel Mo(W)/Cu/S Polymers Containing Thiolato Bridging Ligands

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Abstract

Four novel M/Cu/S polymers [Et4N][MS4Cu3(S2COEt)2] (1a: M=Mo; 1b: M=W) and Et4N][MS4Cu2SEt] (2a: M=Mo; 2b: M=W) have been prepared by reactions of [Et4N]2[MS4] with CuS2COEt and CuSEt. X-ray crystal structure determinations reveal that the polymeric anions of complexes 1a and 1b both consist of MS4Cu3 building blocks linked via bidentate [S2COEt]− bridging ligands to form 1D polymeric chains. The anion structures of the polymeric compounds 2a and 2b contain MS4Cu2 repeating units which are connected via μ-SEt− ligands forming a zigzag chain running down the crystallographic b axis.

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Acknowledgements

This research was supported by grants from the State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences (CAS), the Ministry of Science and Technology of China (001CB108906) and the National Science Foundation of China (20333070).

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Authors and Affiliations

  1. State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou, 350002, P.R. China

    Jianrong Li, Shaowu Du & Xintao Wu

  2. Graduate School of the Chinese Academy of Sciences, Beijing, 100039, P.R. China

    Jianrong Li

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  1. Jianrong Li
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  2. Shaowu Du
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  3. Xintao Wu
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Correspondence to Shaowu Du.

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Li, J., Du, S. & Wu, X. Synthesis and Crystal Structures of Four Novel Mo(W)/Cu/S Polymers Containing Thiolato Bridging Ligands. J Clust Sci 16, 489–500 (2005). https://doi.org/10.1007/s10876-005-0012-2

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