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Ni-Na Coordination Polymer Bridged by Dicyanamide: Synthesis, Structures, Spectra and Thermal Stability

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Abstract

One Ni(II)-Na(I) complex namely {[NiII-L-NaI(dca)]2}n [H2L = 1,2-ethanediylbis(2-iminomethylene-6-methoxy-phenol)] was synthesized under mild conditions at room temperature and characterized by elemental analysis, infrared spectroscopy, X-ray diffraction and thermogravimetric analysis. Single crystal X-ray diffraction analyses show that Ni(II) centers are in four-coordinate D4h geometry and Na(I) centers are in a six-coordinate slightly distorted pentagonal pyramidal C5v geometry in the complex. The basic structural components of the complex are the [NiII-L-NaI] units, which are further connected by the dicyanamide through μ1,5 mode between the Na centers to form 1D chain structures. Thermogravimetric analysis indicate that complex 1 shows good thermal stability.

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Data Availability

The crystallographic data CCDC-2121954 (1) for this paper can be obtained free of charge from The Cambridge Crystallographic Data Centre via www.ccdc.cam.ac.uk/data_request/cif.

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Acknowledgements

We thank the Natural Science Foundation of Shandong Province (ZR2016BB07) and National Natural Science Foundation of China (21901097) for financial support. Thanks for the Foundation of Introduction and Cultivation Program for Young Innovative Talents in Shandong Provincial Colleges and Universities (Innovation Team of Functional Organometallic Materials Presided by Prof. Yanlan Wang).

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering Institution of Functional Organic Molecules and Materials, Liaocheng University, Liaocheng, 252059, China

    Shao-Liang Zhang, Bao-Wei Shen, Xiao-Dong Song & Yan-Lan Wang

  2. School of Geography and Environment, Liaocheng University, Liaocheng, 252059, China

    Shan-Shan Li

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  1. Shao-Liang Zhang
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  2. Bao-Wei Shen
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  3. Xiao-Dong Song
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Correspondence to Shao-Liang Zhang, Yan-Lan Wang or Shan-Shan Li.

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Zhang, SL., Shen, BW., Song, XD. et al. Ni-Na Coordination Polymer Bridged by Dicyanamide: Synthesis, Structures, Spectra and Thermal Stability. J Chem Crystallogr 53, 138–144 (2023). https://doi.org/10.1007/s10870-022-00952-2

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  • DOI: https://doi.org/10.1007/s10870-022-00952-2

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