Skip to main content
SpringerLink
Log in

Synthesis and Crystal Structure of a New Hexavanadate Hybrid with Alkynyl Ligands

  • Original Paper
  • Published:
Journal of Chemical Crystallography Aims and scope Submit manuscript

Abstract

A new hexavanadate hybrid with alkynyl ligands (DIEA)2[V6O13{(OCH2)3CNHCOC6H4C≡CH}2] was synthesized and its molecular structure has been determined by single-crystal X-ray diffraction. The compound crystallize in the orthorhombic system, space group Pccn with the cell parameters a = 15.951(2) Å, b = 33.240 Å, c = 10.5960(14) Å, α = β = γ = 90°, V = 5618.2(13) Å 3. The electrostatic potential was also calculated to show the electron distribution in the polyoxoanion.

Graphical Abstract

A new hexavanadate hybrid with alkynyl ligands (DIEA)2 [V6O13{(OCH2)3CNHCOC6H4C≡CH}2] was synthesized by post-functionalization. Each of the structures looks like a flabellum and both ends are straight and rigid on account of the conjugated effect in the organic ligands.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. Jelinek L, Mitová E, Kubeil M, Stephan H (2021) Solvent Extr Ion Exc 39:1–22

    Article  Google Scholar 

  2. Patel A, Sadasivan R (2021) Prog Mater Sci 118:100759

    Article  CAS  Google Scholar 

  3. Zhong J, Pérez-Ramírez J, Yan N (2021) Green Chem 23:18–36

    Article  CAS  Google Scholar 

  4. Wang X, Zhang T, Li YH, Lin JF, Li H, Wang XL (2020) Inorg Chem 59:17583–17590

    Article  CAS  PubMed  Google Scholar 

  5. Aureliano M, Gumerova NI, Sciortino G, Garribba E, Rompel A, Crans DC (2021) Coordin Chem Rev 447:214143

    Article  CAS  Google Scholar 

  6. Wang JL, Liu XM, Du ZY, Xu Y (2021) Dalton Trans 50:7871–7886

    Article  CAS  PubMed  Google Scholar 

  7. Gu YQ, Li Q, Huang YC, Zhu YT, Wei YG, Ruhlmann L (2020) Chem Commun 56:2869–2872

    Article  CAS  Google Scholar 

  8. Gu YQ, Li Q, Zang DJ, Huang YC, Yu H, Wei YG (2021) Angew Chem Int Ed 60:13310–13316

    Article  CAS  Google Scholar 

  9. Proust A, Matt B, Villanneau R, Guillemot G, Gouzerh P, Izzet G (2012) Chem Soc Rev 41:7605–7622

    Article  CAS  PubMed  Google Scholar 

  10. Bayaguud A, Zhang J, Khan RNN, Hao J, Wei YG (2014) Chem Commun 50:13150–13152

    Article  CAS  Google Scholar 

  11. Chen K, Bayaguud A, Li H, Chu Y, Zhang HC, Jia HL, Zhang BF, Xiao ZC, Wu PF, Liu TB, Wei YG (2018) Nano Res 11:1313–1321

    Article  CAS  Google Scholar 

  12. Zhang JW, Huang YC, Li G, Wei YG (2019) Coord Chem Rev 378:395–414

    Article  CAS  Google Scholar 

  13. Chen K, Jia HL, Liu Y, Yin PC, Wei YG (2020) Adv Biosyst 4:1900281

    Article  CAS  Google Scholar 

  14. Zhu YT, Huang YC, Li Q, Zang DJ, Gu J, Tang YJ, Wei YG (2020) Inorg Chem 59:2575–2583

    Article  CAS  PubMed  Google Scholar 

  15. Wu PF, Xiao ZC, Zhang J, Hao J, Chen JK, Yin PC, Wei YG (2011) Chem Commun 47:5557–5559

    Article  CAS  Google Scholar 

  16. Wang Y, Lin XJ, Huang B, Chen WZ, Xiao ZC, Wu PF (2020) CrystEngComm 22:2434–2438

    Article  CAS  Google Scholar 

  17. Vanhaecht S, Quanten T, Parac-Vogt TN (2017) Dalton Trans 46:10215–10219

    Article  CAS  PubMed  Google Scholar 

  18. Cameron JM, Fujimoto S, Wei RJ, Newton GN, Oshio H (2019) Dalton Trans 47:10590–10594

    Article  Google Scholar 

  19. Fernandez-Navarro L, Nunes-Collado A, Artetxe B, Ruiz-Bilbao E, Felices LS, Reinoso S, Wery AS, Gutierrez-Zorrilla JM (2021) Inorg Chem 60:5442–5445

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  20. Cetindere S, Clausing ST, Anjass M, Luo YS, Kupfer S, Dietzek B, Streb C (2021) Chemistry 27:17181–17187

    Article  CAS  PubMed  PubMed Central  Google Scholar 

  21. Lu BB, Yang J, Che GB, Pei WY, Ma JF (2018) ACS Appl Mater Interfaces 10:2628–2636

    Article  CAS  PubMed  Google Scholar 

  22. Xiong YL, Yu MY, Guo TT, Yang J, Ma JF (2020) Inorg Chem 59:15402–15409

    Article  CAS  PubMed  Google Scholar 

  23. Linnenberg O, Kondinski A, Stöcker C, Monakhov KY (2017) Dalton Trans 46:15636–15640

    Article  CAS  PubMed  Google Scholar 

  24. Jia HL, Li Q, Bayaguud A, Huang YC, She S, Chen K, Wei YG (2018) Dalton Trans 47:2821–2821

    Article  CAS  PubMed  Google Scholar 

  25. Spek AL (2009) Acta Cryst D65:148–155

    Google Scholar 

  26. Dolomanov OV, Bourhis LJ, Gildea RJ, Howard JAK, Puschmann H (2009) J Appl Cryst 42:339–341

    Article  CAS  Google Scholar 

  27. Lu T, Chen FW (2012) J Comput Chem 33:580–592

    Article  PubMed  Google Scholar 

  28. Humphrey W, Dalke A, Schulten K (1996) J Mol Graph 14:33–38

    Article  CAS  PubMed  Google Scholar 

Download references

Acknowledgements

This work is supported by the National Natural Science Foundation of China (No. 21271068, 21401050).

Author information

Author notes

  1. Xingyue Wang and Chunhui Ma have contributed equally.

Authors and Affiliations

  1. Institute of POM-Based Materials, Hubei Provincial Key Laboratory of Green Materials for Light Industry, Hubei University of Technology, Wuhan, 430068, China

    Xingyue Wang, Chunhui Ma, Chenqi Zhao, Yanchao Zhao, Taozhu Zhan, Lihong Chen, Zicheng Xiao & Pingfan Wu

Authors
  1. Xingyue Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Chunhui Ma
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Chenqi Zhao
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Yanchao Zhao
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Taozhu Zhan
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Lihong Chen
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Zicheng Xiao
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. Pingfan Wu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Zicheng Xiao or Pingfan Wu.

Ethics declarations

Conflict of interest

The authors have no relevant financial or non-financial interests to disclose.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Wang, X., Ma, C., Zhao, C. et al. Synthesis and Crystal Structure of a New Hexavanadate Hybrid with Alkynyl Ligands. J Chem Crystallogr 53, 75–80 (2023). https://doi.org/10.1007/s10870-022-00943-3

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10870-022-00943-3

Keywords

Search

Navigation