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Syntheses and Structures of Diphenyl-Tellurium Oxide Copper(II)/Manganese(III) Complexes [CuII(Ph2TeO)4]Cl2·14H2O and [MnIIICl(Ph2TeO)4]Cl2·4H2O

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Abstract

Treatment of diphenyl tellurium oxide (Ph2TeO) with CuCl2·2H2O in a 4:1 molar ratio afforded the copper(II) complex [CuII(Ph2TeO)4]Cl2·14H2O (1), in which the copper(II) center is four-coordinated by four oxygen atoms from four Ph2TeO units. Reaction of MnCl2·4H2O, (nBu4N)[MnO4] and Ph2TeO at a molar ratio of 4:1:16 gave the manganese(III) complex [MnIIICl(Ph2TeO)4]Cl2·4H2O (2), in which the manganese(III) center is five-coordinated by one chlorine atom and four oxygen atoms from four Ph2TeO moieties. Complex 1 crystallizes in the triclinic space group Pī, with a = 8.9904(18), b = 13.068(3), c = 13.573(3) Å, α = 100.42(3)°, β = 109.17(3)°, γ = 99.56(3)°, and Z = 1. The unit cell of 2 has a monoclinic P21/c symmetry with the cell parameters a = 20.179(5), b = 13.917(3), c = 19.210(4) Å, β  =  94.840(7)°, and Z = 4.

Graphical Abstract

Two new transition metal complexes with diphenyl tellurium oxide as ligands have been synthesized and studied.

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Scheme 1
Fig. 1
Fig. 2

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The data is stored on Dropbox and on computers at Anhui University of Technology.

References

  1. Hirpo W, Dhingra S, Sutorik AC, Kanatzidis MG (1993) J Am Chem Soc 115:1597

    Article  CAS  Google Scholar 

  2. Vittal JJ, Ng MT (2006) Acc Chem Res 39:869

    Article  CAS  PubMed  Google Scholar 

  3. Fuhrmann D, Severin T, Krautscheid H, Anorg Z (2017) Allg Chem 643:932

    Article  CAS  Google Scholar 

  4. Back D, de Oliveira GM, Lang ES (2015) Polyhedron 85:565

    Article  CAS  Google Scholar 

  5. Beckmann J, Bolsinger J, Duthie A, Fink P (2012) Organometallics 31:238

    Article  CAS  Google Scholar 

  6. Barton DHR, Ley SV, Meerholz CA (1979) J Chem Soc Chem Commun 17:755

    Article  Google Scholar 

  7. Engman L, Cava MP (1981) Tetrahedron Lett 22:5251

    Article  CAS  Google Scholar 

  8. Mallow O, Bolsinger J, Finke P, Hesse M, Chen YS, Duthie A, Grabowsky S, Luger P, Mebs S, Beckmann J (2014) J Am Chem Soc 136:10870

    Article  CAS  PubMed  Google Scholar 

  9. Xue M, Gao Y-C, Shen J-K, Shi Q-Z, Basolo F (1993) Inorg Chim Acta 207:207

    Article  CAS  Google Scholar 

  10. Okada Y, Oba M, Arai A, Tanaka K, Nishiyama K, Ando W (2010) Inorg Chem 49:383

    Article  CAS  PubMed  Google Scholar 

  11. You Y, Ahsan K, Detty MR (2003) J Am Chem Soc 125:4918

    Article  CAS  PubMed  Google Scholar 

  12. Beckmann J, Dakternieks D, Duthie A, Lewcenko NA, Mitchell C (2004) Angew Chem Int Ed 43:6683

    Article  CAS  Google Scholar 

  13. Beckmann J, Dakternieks D, Duthie A, Mitchell C (2005) Dalton Trans 9:1563–1564

    Google Scholar 

  14. Srungavruksham NK, Baskar V (2015) Dalton Trans 44:6358

    Article  CAS  PubMed  Google Scholar 

  15. Xu C, Zhang JJ, Chen Q, Duan T, Leung WH, Zhang QF (2012) Inorg Chem Commun 21:1

    Article  Google Scholar 

  16. Wang Y-J, Hu F, Jia A-Q, Shi H-T, Zhang QF (2015) Z Naturforsch 70:361

    Article  CAS  Google Scholar 

  17. Cui Y-J, Hu F, Jia A-Q, Xin Z-F, Zhang Q-F (2018) J Coord Chem 71:2183

    Article  CAS  Google Scholar 

  18. SMART and SAINT+ for Windows NT (version 6.02a) [CP]. Bruker Analytical X-ray Instruments Inc., Madison, Wisconsin (USA) (1998)

  19. Sheldrick GM (1997) Sadabs, program for scaling and correction of area detector data. University of Göttingen, Göttingen

    Google Scholar 

  20. Sheldrick GM (1997) Shelxtl (version 5.1) Software Reference Manual, Bruker AXS Inc., Madison

  21. Sheldrick GM (2008) Acta Crystallogr A 64:112

    Article  CAS  PubMed  Google Scholar 

  22. Aromí G, Knapp MJ, Claude J-P, Huffman JC, Hendrickson DN, Christo G (1999) J Am Chem Soc 121:5489

    Article  Google Scholar 

  23. Alcock NW, Harrison WD (1982). J Chem Soc Dalton Trans. https://doi.org/10.1039/dt9820000709

    Article  Google Scholar 

  24. Oba M, Okada Y, Endo M, Tanaka K, Nishiyama K, Shimada S, Ando W (2010) Inorg Chem 49:10680

    Article  CAS  PubMed  Google Scholar 

  25. Mos A, Strobele M, Meyer H-J, Anorg Z (2015) Allg Chem 641:2245

    Article  CAS  Google Scholar 

  26. Thirumoorthia R, Chandrasekhar V (2019) Inorg Chim Acta 497:119092

    Article  Google Scholar 

  27. Do TG, Hupf E, Lork E, Beckmann J (2018) Molecules 23:2805

    Article  PubMed  PubMed Central  Google Scholar 

Download references

Acknowledgements

This project was supported by provincial foundation for excellent young talents of colleges and universities of Anhui province (gxyqZD2021105).

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  1. Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma’anshan, 243002, Anhui, People’s Republic of China

    Qian-Ya Xu, Yu-Jie Cui, Feng Hu, Ai-Quan Jia & Qian-Feng Zhang

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Xu, QY., Cui, YJ., Hu, F. et al. Syntheses and Structures of Diphenyl-Tellurium Oxide Copper(II)/Manganese(III) Complexes [CuII(Ph2TeO)4]Cl2·14H2O and [MnIIICl(Ph2TeO)4]Cl2·4H2O. J Chem Crystallogr 53, 1–7 (2023). https://doi.org/10.1007/s10870-022-00942-4

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