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Synthesis and Crystal Structures of Two Cd(II) Coordination Polymers Assembled by 4-Carboxymethoxy-3-phenylacrylic Acid Ligands

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Abstract

Two Cd(II) complexes, [Cd(CMOPAA)(Phen)(H2O)]n (1) and [Cd(CMOPAA)(Bipy)]n (2), (H2CMOPAA = 4-carboxymethoxy-3-phenylacrylic acid, Phen = 1,10-phenanthroline and 2,2′-bipyridine = Bipy) were synthesized with 4-carboxymethoxy-3-phenylacrylic acid ligands by solvothermal condition and structurally characterized by element analysis, IR, TGA and single crystal X-ray diffraction. Complex 1 crystalizes in the monoclinic system, space group C2/c with a = 12.4609 (11) Å, b = 18.7973 (16) Å, c = 13.4544 (12) Å, β = 99.732 (1)°, V = 3106.1 (5) Å3. The asymmetric unit of complex 1 consists of one Cd(II) ion, one CMOPAA2− ligand, one Phen ligand and one H2O. Cd(II) ion is an eight-coordinated distorted dodecahedron geometry. Each CMOPAA2− ligand coordinates with two adjacent Cd(II) ions to form a one-dimensional chain. Complex 2 crystalizes in the triclinic system, space group P-1 with a = 9.407 (3) Å, b = 9.838 (3) Å, c = 11.792 (4) Å, α = 83.974 (4)°, β = 78.392 (3)°, γ = 67.019 (3)°, V = 983.7 (5) Å3. The asymmetric unit of complex 2 consists of one Cd(II) ion, one CMOPAA2− ligand and one Bipy ligand. Cd(II) ion is a seven-coordinated twisted single-cap triangular prism configuration. The hexadentate bridging CMOPAA2− ligands coordinates with four adjacent Cd(II) ions to form a one-dimensional chain. The tetradentate bridging CMOPAA2− ligands link the neighboring one-dimensional chains to form a novel two-dimensional network structure.

Graphical Abstract

Two Cd(II) complexes, [Cd(CMOPAA)(Phen)(H2O)]n (1) and [Cd(CMOPAA)(Bipy)]n (2), (H2CMOPAA = 4-carboxymethoxy-3-phenylacrylic acid, Phen = 1,10-phenanthroline and 2,2′-bipyridine = Bipy) were synthesized with 4-carboxymethoxy-3-phenylacrylic acid ligands and structurally characterized by element analysis, IR, TGA and single crystal X-ray diffraction. Complex 1 is a one-dimensional chain and complex 2 is a two-dimensional network structure.

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Data Availability

Data Availability CCDC 2,094,699–2,094,700 contain the supplementary crystallographic data for 1–2. These data can be obtained free of charge from the Cambridge Crystallographic Data Centre via www.ccdc.cam. ac.uk/structures.

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Acknowledgements

This work was supported by The Research Foundation of Educational Department of Jiangxi Province [No. GJJ200404]. X-ray data were collected at Instrumental Analysis Center Nanchang Hangkong University, Nanchang, 330063, People's Republic of China.

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Authors and Affiliations

  1. College of Chemistry and Material, Jiangxi Agricultural University, Nanchang, 330045, China

    Pan-Lei Xiao, Jia Gu, Da-Yong Peng, Wan-Ming Xiong & Xu-Liang Nie

  2. Key Laboratory of Chemical Utilization of Plant Resources of Nanchang, Nanchang, 330045, China

    Da-Yong Peng, Wan-Ming Xiong & Xu-Liang Nie

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  1. Pan-Lei Xiao
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  2. Jia Gu
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Xiao, PL., Gu, J., Peng, DY. et al. Synthesis and Crystal Structures of Two Cd(II) Coordination Polymers Assembled by 4-Carboxymethoxy-3-phenylacrylic Acid Ligands. J Chem Crystallogr 53, 16–24 (2023). https://doi.org/10.1007/s10870-022-00938-0

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